Results 171 to 180 of about 7,765 (231)
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Formation of Scalemic Aziridines via the Nucleophilic Opening of Aziridines
The Journal of Organic Chemistry, 1997Introduction As part of our work in the preparation of aziridineallylsilanes1 we had need of a method for the preparation of simple monosubstituted, scalemic aziridines such as 1. The preparation of scalemic aziridines has been well covered in a number of reviews.2 Two methods seemed particularly well suited for the preparation of the types of ...
Stephen C., Bergmeier, Punit P., Seth
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ChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
Mikio, Sasaki +2 more
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Mikio, Sasaki +2 more
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Catalyst-free aziridination and unexpected homologation of aziridines from imines
Organic & Biomolecular Chemistry, 2010Aziridination and unpredicted homologation reaction of N-sulfonylimines were achieved easily with a very simple, rapid and mild procedure through the use of diazomethane without the presence of any catalyst. The method represents an attractive alternative to metal-catalyzed processes.
Paula Sério, Branco +3 more
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Organocatalytic Asymmetric Aziridination of Enones
Angewandte Chemie International Edition, 2008A primary amine derived from cinchona alkaloids as a salt with d-N-Boc phenylglycine (Boc = tert-butoxycarbonyl) is an efficient catalyst for the aziridination of α,β-unsaturated ketones. This method is effective with both linear and cyclic substrates, leading to chiral aziridines in high yield, with complete diastereoselectivity, and with very high ...
PESCIAIOLI, FABIO +6 more
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An Amine‐Promoted Aziridination of Chalcones.
ChemInform, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Yu-Mei, Shen +3 more
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Chemistry of Carbohydrate Aziridines
2006Publisher Summary This chapter discusses the chemistry of carbohydrate aziridines, with emphasis being placed on surveying preparative methods and ring-opening reactions. Carbohydrate aziridines or epimines are derivatives in which an aziridine ring is fused to a pyranose or furanose ring or to an exocyclic part of a carbohydrate molecule.
Jindrich, Karban, Jirí, Kroutil
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ChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Albert Padwa, S. Shaun Murphree
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AbstractFor Abstract see ChemInform Abstract in Full Text.
Albert Padwa, S. Shaun Murphree
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Asymmetric Catalytic Aziridination to Synthesize Spiro‐aziridine Oxindoles
Chemistry – A European JournalAbstractAsymmetric catalytic aza‐Michael‐initiated ring closure of methyleneindolinones with N‐tosyloxycarbamates has been established. The reaction using a chiral nickel complex catalyst enabled the formation of a series of spiro‐aziridine oxindoles in good yields (up to 99 %) with high stereoselectivity (up to 97 % ee, >19 : 1 dr) under mild ...
Yinhe Qu +4 more
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ChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
M. M. Faul, D. A. Evans
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AbstractFor Abstract see ChemInform Abstract in Full Text.
M. M. Faul, D. A. Evans
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A probable aziridine radical: mechanism of addition of aziridine to styrenes
Journal of the Chemical Society D: Chemical Communications, 1969Strong evidence of an aziridine radical in the sodium-catalysed addition of aziridine to styrenes has been obtained.
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