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Substituted Aziridines by Lithiation—Electrophile Trapping of Terminal Aziridines. [PDF]
ChemInform, 2005 AbstractFor Abstract see ChemInform Abstract in Full Text.
Hodgson, D, Humphreys, P, Ward, J
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Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines
Beilstein Journal of Organic Chemistry, 2013 Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2.
Ashley N. Jarvis +3 more
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Synthesis of oxazolinyl aziridines
Tetrahedron Letters, 1999 Abstract Aziridinyllithiums 4a and 4b , which are stable at low temperature, can be generated by deprotonation of 3a and 3b . Oxazolinyl aziridines 5a-j and 6a-b have been prepared by the reaction of oxazolinyl aziridinyllithiums 4a and 4b with electrophiles. Aziridines 6c and 6d were, instead, synthesized by a Darzens-like reaction
S. FLORIO +3 more
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Organocatalyzed enantioselective desymmetrization of aziridines and epoxides
Beilstein Journal of Organic Chemistry, 2013 Enantioselective desymmetrization of meso-aziridines and meso-epoxides with various nucleophiles by organocatalysis has emerged as a cutting-edge approach in recent years.
Ping-An Wang
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Mechanistic Insights into Lewis Acid-Catalyzed Formal [3 + 2] Cycloadditions of Aziridines: A Molecular Electron Density Theory Study [PDF]
MoleculesThe Lewis acid (LA)-promoted formal [3 + 2] cycloaddition (32CA) reaction of 2-phenyl-1-tosylaziridine (2PTA) with ketone has been studied within the framework of Molecular Electron Density Theory (MEDT) at the ωB97X-D/6-311G(d,p) computational level in ...
Luis R. Domingo +2 more
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Dimerization of Lithiated Terminal Aziridines
Angewandte Chemie - International Edition, 2006 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
David M Hodgson
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ARKIVOC, 2007 The reactivity of 1-alkyl-2-(bromomethyl)aziridines with respect to different types of oxygen-, nitrogen- and sulphur-centered nucleophiles has been evaluated, pointing to the conclusion that these substrates can be applied successfully as synthetic ...
Matthias D’hooghe, Norbert De Kimpe
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Aziridines: epoxides’ ugly cousins?
Chem. Soc. Rev., 2002 AbstractFor Abstract see ChemInform Abstract in Full Text.
Sweeney, Joseph B.
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A Review on Recent Approaches to the Asymmetric Synthesis of Aziridines Derivatives [PDF]
Journal of Chemistry Letters, 2021 The aziridines are an important class of heterocyclic compounds that are used for the synthesis of high valuable compounds containing biological and natural products.
Farahnaz Salimi +2 more
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N-Aminopyridinium reagents as traceless activating groups in the synthesis of N-Aryl aziridines
Nature Communications, 2022 Aziridines are useful intermediates, present in important synthetic targets. Here, the authors show a strategy for the synthesis of N-aryl aziridines based on N-aminopyridinium reagents followed by Ni-catalyzed C–N cross-coupling of N-pyridinium ...
Hao Tan +4 more
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