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Ring-Opening Fluorination of Isoxazoles [PDF]
A ring-opening fluorination of isoxazoles has been developed. By treating isoxazoles with an electrophilic fluorinating agent (Selectfluor®), fluorination followed by deprotonation leads to tertiary fluorinated carbonyl compounds. The present method features mild reaction conditions, good functional group tolerance, and simple experimental procedure ...
Masaaki Komatsuda +4 more
core +5 more sources
Unexplored Nucleophilic Ring Opening of Aziridines
The reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields g-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles.
Ana María Costero +3 more
openaire +4 more sources
Alkylative Aziridine Ring-Opening Reactions
In this study, the highly strained three-membered aziridine ring was successfully activated as the aziridinium ion by alkylation of the ring nitrogen with a methyl, ethyl or allyl group, which was followed by ring opening with external nucleophiles such ...
Jieun Choi, Taehwan Yu, Hyun-Joon Ha
doaj +1 more source
Oxidative Arene Ring-Opening of Benzylic Alcohols. [PDF]
Zhu MH +6 more
europepmc +2 more sources
Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization.
Penczek Stanislaw +2 more
doaj +1 more source
Recent advances using cyclopropanols and cyclobutanols in ring-opening asymmetric synthesis
Due to high ring strain energies, cyclopropanols and cyclobutanols have a strong tendency of breaking the endocyclic C–C bonds to participate in versatile organic transformations.
Hong Yan, Gregory S. Smith, Fen-Er Chen
doaj +1 more source
Alkylating ability of carbohydrate oxetanes: Practical synthesis of bolaform skeleton derivative [PDF]
Alkylating ability of oxetane ring in carbohydrate structure was investigated and flexible method for bolaform amphiplile skeleton construction with xylose as polar heads is proposed.
Hadžić Pavle A. +2 more
doaj +1 more source
Special Issue “Ring-Opening Polymerization”
n ...
Takeshi Endo, Atsushi Sudo
doaj +1 more source
Synthesis and Membrane Properties of Troger′s Base Polymers
Troger′s base polymers have strong chemical stability, thermal stability and rigidity, V-shaped ladder structure and porous structure. The nitrogen heterocyclic ring is hydrophilic.
HUANG Ronglu; ZHANG Chen; WANG Yuyong; TANG Hai; ZHANG Ze
doaj +1 more source
Si-Imidazole-HSO4 Functionalized Magnetic Fe3O4 Nanoparticles as an Efficient and Reusable Catalyst for the Regioselective Ring Opening of Epoxides in Water [PDF]
An efficient and simple method for the preparation of Si-Imidazole-HSO4 functionalized magnetic Fe3O4 nanoparticles (Si-Im-HSO4 MNPs) and used as an efficient and reusable magnetic catalysts for the regioselective ring opening of epoxides under green ...
Eshagh Rezaee Nezhad +1 more
doaj +1 more source

