Ring-opening polymerization [PDF]
Chemistry Teacher International, 2021 Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization.
Penczek Stanislaw +2 more
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Aromatic ring-opening metathesis. [PDF]
NatureAbstract Aromatic compounds are used across chemistry and materials science as a result of their stability, characteristic interactions, defined molecular shape and the numerous approaches for their synthesis by a diversity of cyclization reactions 1 .
Hutskalova V, Sparr C.
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Dispersity-controlled ring-opening polymerization of epoxide [PDF]
Nature CommunicationsDispersity or molar mass distribution (Ð M) profoundly influences polymer properties, but its control remains a challenge, especially for ring-opening polymerization (ROP).
Yubo Zhou, Junpeng Zhao, Guangzhao Zhang
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Straightforward Synthetic Approach to Aminoalcohols with 9-oxabicyclo[3.3.1]nonane or Cyclooctane Core via Nucleophilic Ring-Opening of Spirocyclic Bis(oxiranes) [PDF]
MoleculesNucleophilic ring-opening of bis(oxiranes), containing several reactive centers, can be used to elaborate straightforward atom-economy and stereoselective approaches to polyfunctionalized compounds.
Olga V. Ryzhikova +6 more
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Recoverable Fluorination Accelerates Ring-Opening Copolymerisation and Enables Post-Polymerisation-Modification of Polyesters. [PDF]
Angew Chem Int Ed EnglFornacon-Wood C +4 more
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Alkylative Aziridine Ring-Opening Reactions
Molecules, 2021 In this study, the highly strained three-membered aziridine ring was successfully activated as the aziridinium ion by alkylation of the ring nitrogen with a methyl, ethyl or allyl group, which was followed by ring opening with external nucleophiles such ...
Jieun Choi, Taehwan Yu, Hyun-Joon Ha
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Recent advances using cyclopropanols and cyclobutanols in ring-opening asymmetric synthesis
Green Synthesis and Catalysis, 2022 Due to high ring strain energies, cyclopropanols and cyclobutanols have a strong tendency of breaking the endocyclic C–C bonds to participate in versatile organic transformations.
Hong Yan, Gregory S. Smith, Fen-Er Chen
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Carbodiimide Ring-opening Metathesis Polymerization
ACS Central Science, 2022 Controlled incorporation of nitrogen into macromolecular skeletons is a long-standing challenge whose resolution would enable the preparation of soft materials with the scalability of man-made plastics and functionality of Nature’s proteins. Nylons and polyurethanes notwithstanding, nitrogen-rich polymer backbones remain scarce, and their synthesis ...
J. Drake Johnson +6 more
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Alkylating ability of carbohydrate oxetanes: Practical synthesis of bolaform skeleton derivative [PDF]
Journal of the Serbian Chemical Society, 2015 Alkylating ability of oxetane ring in carbohydrate structure was investigated and flexible method for bolaform amphiplile skeleton construction with xylose as polar heads is proposed.
Hadžić Pavle A. +2 more
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Kinetics and mechanism of the conversion of cyclobutenones to vinylketens [PDF]
, 1976 The structure–rate relationships for the electrocyclic ring opening of phenylated and alkylated cyclobutenones to vinylketens, though not fully understood, resemble those which are observed in cyclobutene ring ...
Huisgen, Rolf, Mayr, Herbert
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