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Ring-Opening Fluorination of Isoxazoles [PDF]

open access: yesOrganic Letters, 2022
A ring-opening fluorination of isoxazoles has been developed. By treating isoxazoles with an electrophilic fluorinating agent (Selectfluor®), fluorination followed by deprotonation leads to tertiary fluorinated carbonyl compounds. The present method features mild reaction conditions, good functional group tolerance, and simple experimental procedure ...
Masaaki Komatsuda   +4 more
core   +5 more sources

Unexplored Nucleophilic Ring Opening of Aziridines

open access: yesMolecules, 2010
The reactivity of dianions of carboxylic acids towards aziridines has been studied. Although, a similar reactivity to that of enolates from ketones, esters or amides has been observed, the method directly yields g-aminoacids in one step. The method is complementary of previous results of enenediolate reactivity with other electrophiles.
Ana María Costero   +3 more
openaire   +4 more sources

Alkylative Aziridine Ring-Opening Reactions

open access: yesMolecules, 2021
In this study, the highly strained three-membered aziridine ring was successfully activated as the aziridinium ion by alkylation of the ring nitrogen with a methyl, ethyl or allyl group, which was followed by ring opening with external nucleophiles such ...
Jieun Choi, Taehwan Yu, Hyun-Joon Ha
doaj   +1 more source

Oxidative Arene Ring-Opening of Benzylic Alcohols. [PDF]

open access: yesJACS Au
Zhu MH   +6 more
europepmc   +2 more sources

Ring-opening polymerization

open access: yesChemistry Teacher International, 2021
Ring-opening polymerization is defined by IUPAC (Penczek, S., Moad, G. (2008). Glossary of the terms related to kinetics, thermodynamics, and mechanisms of polymerization.
Penczek Stanislaw   +2 more
doaj   +1 more source

Recent advances using cyclopropanols and cyclobutanols in ring-opening asymmetric synthesis

open access: yesGreen Synthesis and Catalysis, 2022
Due to high ring strain energies, cyclopropanols and cyclobutanols have a strong tendency of breaking the endocyclic C–C bonds to participate in versatile organic transformations.
Hong Yan, Gregory S. Smith, Fen-Er Chen
doaj   +1 more source

Alkylating ability of carbohydrate oxetanes: Practical synthesis of bolaform skeleton derivative [PDF]

open access: yesJournal of the Serbian Chemical Society, 2015
Alkylating ability of oxetane ring in carbohydrate structure was investigated and flexible method for bolaform amphiplile skeleton construction with xylose as polar heads is proposed.
Hadžić Pavle A.   +2 more
doaj   +1 more source

Special Issue “Ring-Opening Polymerization”

open access: yesMolecules, 2016
n ...
Takeshi Endo, Atsushi Sudo
doaj   +1 more source

Synthesis and Membrane Properties of Troger′s Base Polymers

open access: yesNantong Daxue xuebao. Ziran kexue ban, 2020
Troger′s base polymers have strong chemical stability, thermal stability and rigidity, V-shaped ladder structure and porous structure. The nitrogen heterocyclic ring is hydrophilic.
HUANG Ronglu; ZHANG Chen; WANG Yuyong; TANG Hai; ZHANG Ze
doaj   +1 more source

Si-Imidazole-HSO4 Functionalized Magnetic Fe3O4 Nanoparticles as an Efficient and Reusable Catalyst for the Regioselective Ring Opening of Epoxides in Water [PDF]

open access: yesNanochemistry Research, 2016
An efficient and simple method for the preparation of Si-Imidazole-HSO4 functionalized magnetic Fe3O4 nanoparticles (Si-Im-HSO4 MNPs) and used as an efficient and reusable magnetic catalysts for the regioselective ring opening of epoxides under green ...
Eshagh Rezaee Nezhad   +1 more
doaj   +1 more source

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