Results 51 to 60 of about 3,434 (226)

Investigation on the reactivity of α-azidochalcones with carboxylic acids: Formation of α-amido-1,3-diketones and highly substituted 2-(trifluoromethyl)oxazoles

open access: yesBeilstein Journal of Organic Chemistry, 2015
The reaction of α-azidochalcones with carboxylic acids has been investigated resulting in the formation of α-amido-1,3-diketones under microwave irradiation via in situ formation of 2H-azirine intermediates.
Kandasamy Rajaguru   +4 more
doaj   +1 more source

Reaktionen von 3-Dimethylamino-2,2-dimethyl-2H-azirin mit aromatischen Carbonsäurehydraziden

open access: yesCHIMIA, 1978
Reaction of 3-dimethylamino-2,2-dimethyl-2H-azirine (1) with salicylic acid hydrazide (2c) in acetonitrile at room temperature gives the amidrazone 3c as a primary product in 78% yield. Cyclization of 3c in methanol leads to the 1,2,5,6-tetrahydro-1,2,4-
Stanislav Chaloupka, Heinz Heimgartner
doaj   +1 more source

Inductive queries for a drug designing robot scientist [PDF]

open access: yes, 2010
It is increasingly clear that machine learning algorithms need to be integrated in an iterative scientific discovery loop, in which data is queried repeatedly by means of inductive queries and where the computer provides guidance to the experiments that ...
A. Lingas   +10 more
core   +1 more source

Asymmetric organocascades involving the formation of two C-heteroatom bonds from two distinct heteroatoms [PDF]

open access: yes, 2012
International audienceIn the vast and expanding world of enantioselective organocascades, the ones in which two C-heteroatom bonds are created from two distinct heteroatoms are rare.
Bonne, Damien   +3 more
core   +3 more sources

Reactivity of 2-halo-2H-azirines. Part 3: Dehalogenation of 2-halo-2H-azirine-2-carboxylates [PDF]

open access: yesTetrahedron, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
Pinho e Melo, Teresa M. V. D.   +2 more
openaire   +2 more sources

Synthesis of New 2-Halo-2-(1H-tetrazol-5-yl)-2H-azirines via a Non-Classical Wittig Reaction

open access: yesMolecules, 2015
The synthesis and reactivity of tetrazol-5-yl-phosphorus ylides towards N-halosuccinimide/TMSN3 reagent systems was explored, opening the way to new haloazidoalkenes bearing a tetrazol-5-yl substituent.
Ana L. Cardoso   +4 more
doaj   +1 more source

Accurate ring strain energies of unsaturated three-membered heterocycles with one group 13–16 element [PDF]

open access: yes, 2022
© 2022 The Authors. This manuscript version is made available under the CC-BY 4.0 license http://creativecommons.org/licenses/by/4.0/ This document is the Published Manuscript version of a Published Work that appeared in final form in Inorganic ...
Espinosa Ferao, Arturo   +1 more
core   +1 more source

Diverse reactivity of maleimides in polymer science and beyond

open access: yesPolymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick   +2 more
wiley   +1 more source

Synthesis of Isoxazole- and Oxazole-4-carboxylic Acids Derivatives by Controlled Isoxazole-Azirine-Isoxazole/Oxazole Isomerization.

open access: yesJournal of Organic Chemistry, 2019
The first synthesis of isoxazole-4-carboxylic acid derivatives by domino isoxazole-isoxazole isomerization is reported. Fe(II)-catalyzed isomerization of 4-acyl-5-methoxy-/5-aminoisoxazoles (dioxane, 105 °C) leads to the formation of isoxazole-4 ...
A. V. Serebryannikova   +3 more
semanticscholar   +1 more source

Composite Single‐Reference and Explicitly Correlated Multireference Calculations on the Mechanism of Pyrrole Pyrolysis

open access: yesJournal of Physical Organic Chemistry, Volume 39, Issue 4, April 2026.
New calculations have been applied to the pyrolysis of pyrrole under shock‐tube conditions and to the radical‐radical reaction between allyl and •CN at low temperature and pressure, using the same mechanistic scheme for both. ABSTRACT The pyrolysis of pyrrole has previously been studied in shock‐tube experiments and in jet‐stirred reactors. The results
Barry K. Carpenter
wiley   +1 more source

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