Metallkomplexe mit biologisch wichtigen Liganden, LXX [PDF]
Metal Complexes of Biologically Important Ligands, LXX[1].- Synthesis, Stereochemistry and Reactions of Ruthenium(II) and Osmium(II) Complexes with -Amino Carboxylates[Note ][Herrn Professor Helmut Werner zum 60.
Ahmad +33 more
core +1 more source
Development of a Copper‐Free Click Reaction for Asymmetric Rh Diene Catalysis Under Confinement
A copper‐free amino–yne click reaction enables the selective functionalization of chiral diene ligands with both soluble and immobilized amines. Substituent‐controlled stereoselectivity affords (E)‐ and (Z)‐enaminone ligands, which are converted into Rh complexes for asymmetric catalysis under homogeneous and heterogeneous conditions.
Manuel Kirchhof +10 more
wiley +1 more source
Synthesis of 2-Aminonicotinonitriles via Photodecarboxylation of Azirine-2-Carboxylic Acids
2-Aminonicotinonitriles represent an important class of heterocycles with diverse biological activities. Herein, we report an unexpected photochemical transformation of azirine-2-carboxylic acids leading to the formation of 2-aminonicotinonitrile ...
Julia I. Pavlenko +2 more
doaj +1 more source
Synthetic Strategies to Access Fluorinated Azoles
This review highlights recent synthetic strategies for introducing fluorine groups (mono‐, di‐, and trifluoromethylation) into 11 major azole classes, identifying research gaps to inform future innovations in materials science, medicinal chemistry, and biomedical research.
Mohammed K. Abd El‐Gaber +4 more
wiley +1 more source
2H-Pyrrole und Pyrrole aus 3-Phenyl-2H-azirinen
Vinyl-phosphonium salts [2] and phenyl-vinyl-sulfone or divinylsulfone react with benzonitril-methylides a (which are photochemically generated from 3-phenyl-2H-azirines 1 and 2) to give, via the nonisolated intermediates of type b, 2H-pyrrole 4 and the
Ulrich Widmer +4 more
doaj +1 more source
Der Einbau verschiedener Chalkogenatome (O, S, Se oder Te) in häufig verwendete Isochalkogenharnstoff‐Organokatalysatoren ermöglicht die Feinabstimmung ihrer Nucleophilie und Basizität. Kinetische und thermodynamische Deskriptoren für die molekularen Eigenschaften der Katalysatoren werden als Werkzeuge zur Vorhersage ihrer Effizienz eingeführt und in ...
Lotte Stockhammer +8 more
wiley +1 more source
Incorporation of different chalcogen atoms allows for the fine‐tuning of nucleophilicity and basicity of commonly used isochalcogenourea organocatalyst scaffolds. Kinetic and thermodynamic descriptors for the molecular properties of the catalysts are introduced as tools to predict their efficiency and tested in acyl transfer and allenoate activation ...
Lotte Stockhammer +8 more
wiley +1 more source
Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate [PDF]
The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane.
Alves, Maria José Chão +3 more
core
Aziridine and azirine carboxylic esters [PDF]
Abstract
Binne Zwandenburg, L. Thijs
openaire +1 more source
Marine pharmacology in 2009-2011: marine compounds with antibacterial, antidiabetic, antifungal, anti-inflammatory, antiprotozoal, antituberculosis, and antiviral activities; affecting the immune and nervous systems, and other miscellaneous mechanisms of action. [PDF]
The peer-reviewed marine pharmacology literature from 2009 to 2011 is presented in this review, following the format used in the 1998–2008 reviews of this series.
A. D. Rodriguez +3 more
core +2 more sources

