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Iodine‐Mediated Electrochemical Diastereoselective Synthesis of Enaminones
ChemElectroChemAn efficient iodine‐mediated electrochemical method for the synthesis of enaminones from thioamides and organic diazo compounds is reported. The transformation proceeds under mild and sustainable conditions, using electric current and avoiding the need ...
Ijaz Khan +2 more
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Nature Communications, 2020 Strategies for enantioselective α-aminomethylation of carbonyl compounds rely on the chiral activation of stable ketones substrate. Here, the authors report a rhodium/chiral phosphoric acid cooperative catalysis for the three-component reaction of α ...
Jiuwei Che +4 more
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Recent Advances in the Synthesis of Aromatic Azo Compounds
Molecules, 2023 Aromatic azo compounds have -N=N- double bonds as well as a larger π electron conjugation system, which endows aromatic azo compounds with wide applications in the fields of functional materials.
Meng-Yun Zhao +2 more
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Facile and diastereoselective arylation of the privileged 1,4-dihydroisoquinolin-3(2H)-one scaffold
Beilstein Journal of Organic Chemistry, 2022 A practically convenient and streamlined protocol for the trans-diastereoselective introduction of an aryl substituent at position 4 of the 1,4-dihydroisoquinol-3-one (1,4-DHIQ) scaffold is presented.
Dmitry Dar’in +3 more
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Access to cyclopropanes with geminal trifluoromethyl and difluoromethylphosphonate groups
Beilstein Journal of Organic Chemistry, 2023 A synthetic route to the bench-stable fluorinated masked carbene reagent diethyl 2-diazo-1,1,3,3,3-pentafluoropropylphosphonate, bearing a trifluoromethyl and a difluoromethyl group is reported for the first time.
Ita Hajdin +5 more
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Conversion of Azides into Diazo Compounds in Water [PDF]
Journal of the American Chemical Society, 2013 Diazo compounds are in widespread use in synthetic organic chemistry but have untapped potential in chemical biology. We report on the design and optimization of a phosphinoester that mediates the efficient conversion of azides into diazo compounds in phosphate buffer at neutral pH and room temperature.
Ho-Hsuan, Chou, Ronald T, Raines
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CXLI.—The rate of decomposition of diazo-compounds. Part I. Diazo-compounds of the benzene series [PDF]
J. Chem. Soc., Trans., 1902 n ...
Cain, John Cannell, Nicoll, Frank
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XXII.—The rate of decomposition of diazo compounds. Part II. Diazo-compounds of the naphthalene series [PDF]
J. Chem. Soc., Trans., 1903 n ...
Cain, John Cannell, Nicoll, Frank
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, 2019 Citation: 'diazo compounds' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.D01691 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
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