Results 11 to 20 of about 21,735 (237)

Preparation and Synthetic Applications of Five-to-Seven-Membered Cyclic α-Diazo Monocarbonyl Compounds

open access: yesMolecules, 2022
The reactivity of cyclic α-diazo monocarbonyl compounds differs from that of their acyclic counterparts. In this review, we summarize the current literature available on the synthesis and synthetic applications of three major classes of cyclic α-diazo ...
Daniil Zhukovsky   +3 more
doaj   +1 more source

Diazocarbonyl and Related Compounds in the Synthesis of Azoles

open access: yesMolecules, 2021
Diazocarbonyl compounds have found numerous applications in many areas of chemistry. Among the most developed fields of diazo chemistry is the preparation of azoles from diazo compounds.
Anton Budeev   +3 more
doaj   +1 more source

Chitosan as a sustainable heterogeneous catalyst for the preparation of functionalized α-diazo carbonyl compounds

open access: yesTetrahedron Green Chem, 2023
The food industry generates vast amounts of waste and one of the most abundant is the biopolymer chitin, which is the main constituent of crustacean shells and insect exoskeletons.
Gabriela M. Diogo   +4 more
doaj   +1 more source

Multicomponent Reactions Involving Diazo Reagents: A 5-Year Update

open access: yesMolecules, 2021
This review summarizes recent developments in multicomponent reactions of diazo compounds. The role of diazo reagent and the type of interaction between components was analyzed to structure the discussion.
Olga Bakulina   +3 more
doaj   +1 more source

A Catalytic Cross-Olefination of Diazo Compounds with Sulfoxonium Ylides. [PDF]

open access: yesAngew Chem Int Ed Engl, 2018
Neuhaus JD, Bauer A, Pinto A, Maulide N.
europepmc   +2 more sources

O-methyltransferase-like enzyme catalyzed diazo installation in polyketide biosynthesis

open access: yesNature Communications, 2023
Diazo compounds are rare natural products possessing various biological activities. Kinamycin and lomaiviticin, two diazo natural products featured by the diazobenzofluorene core, exhibit exceptional potency as chemotherapeutic agents.
Yuchun Zhao   +14 more
doaj   +1 more source

Stereoselective Bioreduction of α-diazo-β-keto Esters

open access: yesMolecules, 2020
Diazo compounds are versatile reagents in chemical synthesis and biology due to the tunable reactivity of the diazo functionality and its compatibility with living systems.
Sergio González-Granda   +3 more
doaj   +1 more source

Synthesis of diversely functionalised 2,2-disubstituted oxetanes: fragment motifs in new chemical space [PDF]

open access: yes, 2015
Novel oxetane motifs incorporating diverse functional groups on the ring are readily accessed by an O–H insertion/cyclisation strategy.
Bull, JA, Croft, RA, Davis, OA
core   +1 more source

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