Results 91 to 100 of about 1,246 (202)

Intermolecular alkyl radical addition to methyl 2-(2,6-Dichlorophenyl)-2H-azirine-3-carboxylate [PDF]

open access: yes, 2012
The 2H-azirine 1 acts as an effective radical acceptor for secondary and tertiary alkyl iodides mediated by triethylborane.
Guimaraes, Emanuel   +3 more
core  

2H-azirine 3-phosphonates: a new class of chiral iminodienophiles. Asymmetric synthesis of quaternary piperidine phosphonates

open access: yes, 2002
Diels−Alder reactions of enantiomerically enriched 2H-azirine 3-phosphonates and dienes stereoselectively furnish optically pure, bicyclic aziridine adducts that on hydrogenation afford the first examples of enantiopure quaternary piperidine ...
Wu, Yongzhong   +9 more
core   +1 more source

PHOTOREACTIONS WITH C60-FULLERENE - [3+2] PHOTOCYCLOADDITION OF 2,3-DIPHENYL-2H-AZIRINE

open access: yes, 1994
AVERDUNG J, ALBRECHT E, LAUTERWEIN J, et al. PHOTOREACTIONS WITH C60-FULLERENE - [3+2] PHOTOCYCLOADDITION OF 2,3-DIPHENYL-2H-AZIRINE. Chemische Berichte. 1994;127(4):787-789.Upon irradiation 2,3-Diphenyl-2H-azirine (2) is added to C60 1 with formation of
Mattay, Jochen   +7 more
core   +1 more source

Photochemistry of 2-(1-Naphthyl)-2H-azirines in Matrixes and in Solutions:  Wavelength-Dependent C−C and C−N Bond Cleavage of the Azirine Ring

open access: yes, 2016
The photochemistry of 3-methyl-2-(1-naphthyl)-2H-azirine (1a) was investigated by the direct observation of reactive intermediates in matrixes at 10 K and by the characterization of reaction products in solutions.
Hiroshi Inui (1935007)   +1 more
core   +1 more source

The Chemistry of Azirines

open access: yesJournal of Synthetic Organic Chemistry, Japan, 1972
TANIGUCHI, Hiroshi, ISOMURA, Kazuaki
openaire   +2 more sources

Unusual Photochemical C−N Bond Cleavage in the Novel Methyl 2-Chloro-3-methyl-2H-azirine-2-carboxylate

open access: yes, 2016
The structure, preferred conformers, vibrational spectrum, and photochemical behavior of the novel azirine, methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) were investigated in low-temperature matrixes and in the neat solid amorphous state by ...
Teresa M. V. D. Pinho e Melo (1724932)   +4 more
core   +1 more source

On the Photochemistry of 1,2-Benzisoxazole: Capture of Elusive Spiro-2H-azirine and Ketenimine Intermediates

open access: yes, 2016
The photochemistry of 1,2-benzisoxazole (1) was studied using low-temperature matrix isolation coupled with infrared spectroscopy and quantum chemistry calculations.
Nunes, Cláudio M.   +3 more
core   +1 more source

1,4,2-Diazaborole-type heterocycle from 2H-azirine-2-carboxylate and [(alkylamino)methyl]trifluoroborate

open access: yes
text学術雑誌論文 / Journal ArticleA 1,4,2-diazaborole-type heterocycle was obtained via addition of [(alkylamino)methyl]-trifluoroborate to 2H-azirine-2-carboxylate. The molecular structure of the product was confirmed by X-ray crystallography.
タカハシ, ヒロト   +9 more
core  

Photochemical Cascade Nitrile Activation via a Carbene-Nitrene Relay. [PDF]

open access: yesAngew Chem Int Ed Engl
Han B   +5 more
europepmc   +1 more source

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