MoleculesThe asymmetric [3+2] cycloaddition of azomethine ylides generated from the corresponding imino ester-to-trans-β-nitrostyrene catalysis by chiral aziridine-containing phosphines and phosphine oxides is described. Of the sixteen stereoisomers that could be
Julia Szymańska +2 more
doaj +1 more source
A one-pot synthesis of tetrahydroisoquinolin-4-ols via a novel acid-catalyzed rearrangement of 5-aryloxazolidines [PDF]
, 2013 Benzaldehydes with electron-donating substituents react smoothly with a nonstabilized azomethine ylide derived from sarcosine and formaldehyde to form 5-aryloxazolidines as intermediates, which undergo rearrangement into 2-methyl-1,2,3,4 ...
Moshkin, V. S., Sosnovskikh, V. Y.
core +1 more source
Addition of azomethine ylides to carbon-encapsulated iron nanoparticles
Dalton Transactions, 2018 Carbon-encapsulated iron nanoparticles have been covalently functionalized using the Prato reaction.
Artur Kasprzak +6 more
openaire +4 more sources
The modification of brucine derivatives as chiral ligands and its application in the asymmetric synthesis [PDF]
, 2014 The modification of brucine derivatives as chiral ligands and the use of a multifaceted chiral ligand, brucine diol, under different reaction conditions to produce various optical isomers is described.
Li, Jian-Yuan
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Electron-rich benzofulvenes as effective dipolarophiles in copper(i)-catalyzed asymmetric 1,3-dipolar cycloaddition of azomethine ylides. [PDF]
Chem Sci, 2023 Chang X +5 more
europepmc +1 more source
A novel SWCNT platform bearing DOTA and b-cyclodextrin units. "One shot" multidecoration under microwave irradiation. [PDF]
, 2014 The functionalization of single-walled carbon nanotubes (SWCNTs) via microwave-assisted grafting reactions enables efficient multidecoration in a single step.
Barge, Alessandro +7 more
core +1 more source
iScience, 2019 Summary: Development of a general catalytic and highly efficient method utilizing readily available precursors for the regio- and stereoselective construction of bioactive natural-product-inspired spiro architectures remains a formidable challenge in ...
Chong Shen +5 more
doaj
Topological Woodward-Hoffmann classification for cycloadditions in polycyclic aromatic azomethine ylides [PDF]
arXivThe study of cycloaddition mechanisms is central to the fabrication of extended sp2 carbon nanostructures. Reaction modeling in this context has focused mostly on putative, energetically preferred, exothermic products with limited consideration for symmetry allowed or forbidden mechanistic effects.
arxiv
11H-Benzo[4,5]imidazo[1,2-a]indol-11-one as a New Precursor of Azomethine Ylides: 1,3-Dipolar Cycloaddition Reactions with Cyclopropenes and Maleimides. [PDF]
Int J Mol Sci, 2022 Filatov AS +6 more
europepmc +1 more source
Enantioselective Synthesis of exo-4-Nitroprolinates from Nitroalkenes and Azomethine Ylides Catalyzed by Chiral Phosphoramidite·Silver(I) or Copper(II) Complexes [PDF]
, 2015 Chiral complexes formed by privileged phosphoramidites derived from chiral binol and optically pure Davies’ amines, and copper(II) triflate, silver(I) triflate or silver(I) benzoate are excellent catalysts for the general 1,3-dipolar cycloaddition ...
Castelló Moncayo, Luis Miguel +5 more
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