Relative Reactivities of Acetals and Ethers under Friedel-Crafts Conditions [PDF]
Competition experiments have been performed to determine the relative reactivities of acetals and ethers toward allyltrimethylsilane in the presence of catalytic amounts of BF3 OEt2.
Dau-Schmidt +11 more
core +1 more source
A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates [PDF]
A practical route to tertiary diarylmethylamides or -carbamates from imines, organozinc reagents and acyl chlorides or chloroformates is described. This route involves the formation of an imine, which is used without isolation, followed by its activation
Bender, Sakurai, Sengmany, Spencer
core +1 more source
An efficient mechanochemical route for diphenyleneiodonium (DPI) salt synthesis is reported which offers a sustainable and solvent‐free alternative. The solid‐state reactivities of the reported DPI salts were also assessed with the help of morphology predictions and Hirshfeld surface analysis computations to understand the effect of crystal morphology,
Ipsha Shruti, Tejender S. Thakur
wiley +1 more source
Asymmetric Ion-Pairing Catalysis [PDF]
Chemistry and Chemical ...
Brak, Katrien, Jacobsen, Eric N.
core +1 more source
Proton Chemical Shifts in Some Benzhydryl Compounds. [PDF]
Leiv J. Stangeland +6 more
openaire +1 more source
Cationic gold(I) heteroleptic complexes bearing a pyrazole-derived N-heterocyclic carbene: syntheses, characterizations, and cytotoxic activities [PDF]
10.1039/c3dt51071aDalton Transactions423412421 ...
Huynh, Han Vinh +2 more
core +1 more source
How Electrophilic are Ferrocenylmethyl Cations? Kinetics of their Reactions with Nucleophiles and Hydride Donors [PDF]
Second-order rate constants for the reactions of the ferrocenylmethylium ions 2a - e with silyl enol ethers, allylsilanes, allylstannanes, and hydride donors have been determined photometrically and conductometrically in dichloromethane.
Arimoto +60 more
core +1 more source
Molecular modeling of biologically active compounds-ligands for GABAa receptors [PDF]
GABAA receptor mediates inhibitory neurotransmission in the central nervous system. A lot of compounds modulating GABAAreceptor and, thus, having anxiolytic or sedative effect has been developed.
Иманкулова, Е. А. +1 more
core
Electrophilicity Equalization Principle
A new electronic structure principle, viz., the principle of electrophilicity equalization is proposed. An analytical justification as well as a numerical support for the same is provided.Comment: 9 pages, 2 ...
Chattaraj, Pratim Kumar +2 more
core +1 more source
Biphenyl-Derived Phosphepines as Chiral Nucleophilic Catalysts: Enantioselective [4+1] Annulations To Form Functionalized Cyclopentenes [PDF]
Because of the frequent occurrence of cyclopentane subunits in bioactive compounds, the development of efficient catalytic asymmetric methods for their synthesis is an important objective.
Fu, Gregory C. +4 more
core +2 more sources

