Results 51 to 60 of about 33,790 (273)

Assembling Hexahedral Supramolecular Nano‐Aggregates on Rice Wax Layer Matrices to Promote the Leaf Deposition and Bioavailability of Bactericides for Plant Protections

open access: yesAdvanced Science, EarlyView.
To address the problem of off‐target movement and low bioavailability of pesticides, two anisotropic supramolecular building units (BiTA18@β‐CD and BiTA18@γ‐CD) have been invented that can self‐assemble into nano‐sized hexagonal cuboids on the rice microcrystalline matrix. This manipulation realizes the enhanced utilization of bactericides for rice and
Run Yang   +4 more
wiley   +1 more source

Research Progress on Benzimidazole Fungicides: A Review

open access: yesMolecules
Benzimidazole fungicides are a class of highly effective, low-toxicity, systemic broad-spectrum fungicides developed in the 1960s and 1970s, based on the fungicidal activity of the benzimidazole ring structure.
Song Bai   +8 more
doaj   +1 more source

Bandgap‐Dependent Doping of Semiconducting Carbon Nanotube Networks by Proton‐Coupled Electron Transfer for Stable Thermoelectrics

open access: yesAdvanced Electronic Materials, EarlyView.
Proton‐coupled electron transfer doping with benzoquinone is applied to p‐dope dense films of semiconducting single‐walled carbon nanotubes. The doping efficiency depends on the pH of the doping solution and the bandgap of the nanotubes. The highest conductivities and power factors are achieved for small‐bandgap nanotubes, remaining stable for over 120
Angus Hawkey   +5 more
wiley   +1 more source

Shaping of a Reactive Manganese Catalyst Enables Access to Polyfunctionalized Cyclohexanes via Enantioselective C(sp3)─H Bond Oxidation of 1,3‐meso Diethers

open access: yesAngewandte Chemie, EarlyView.
Structural shaping of a highly reactive chiral Mn‐oxo species translates into exceptionally enantioselective C─H oxidation catalyst of cyclohexyl 1,3‐meso diethers (up to >99% ee) leading to polyfunctionalized cyclohexanes. Abstract Chiral polyoxygenated cyclohexanes are valuable constituents of biologically relevant products.
Andrea Palone   +7 more
wiley   +2 more sources

Dichloro-Bis(1-cinnamyl-benzimidazole)-Cobalt(II)

open access: yesMolbank
Dichloro-bis(1-cinnamyl-benzimidazole)-cobalt(II) was prepared in one step using a cobalt precursor CoCl2 and corresponding substituted benzimidazole. The complex was fully characterized using IR, elemental analysis, and mass- and NMR spectroscopy.
Neslihan Şahin   +2 more
doaj   +1 more source

Deep Blue Fluorescent OLEDs Based on a Solution and Solid‐State Emitter (SSSE): Investigations with 2‐Phenyl‐Naphthoxazole

open access: yesAdvanced Electronic Materials, EarlyView.
The blue fluorescent molecule 2‐phenyl‐naphth[2,3‐d]oxazole (Nzx) exhibits strong emission in both solution and solid states. Such behavior, referred to as solution and solid‐state emission (SSSE), makes Nzx a promising candidate for optoelectronic applications. This study highlights the potential of Nzx for the development of stable and efficient near
Houssein El Housseiny   +5 more
wiley   +1 more source

Dibromido[1,1′-dibutyl-2,2′-(pentane-1,1-diyl)di-1H-benzimidazole]copper(II)

open access: yesActa Crystallographica Section E, 2010
In the title compound, [CuBr2(C27H36N4)], the CuII ion exhibits a distorted tetrahedral coordination geometry provided by two bromide ions and by chelation of two imine N-atom donors from a bis(benzimidazole) ligand.
Robert T. Stibrany, Joseph A. Potenza
doaj   +1 more source

Understanding the Interplay Between Thermal Activation, Diffusion, and Phase Segregation of Molecular Dopants Blended with Polymeric Semiconductors

open access: yesAdvanced Electronic Materials, EarlyView.
The use of air stable but thermally labile molecules provides an efficient strategy for the N‐type doping of organic semiconductors with relatively low electron affinities. Design criteria for efficient dopants should also take into account diffusion and phase segregation that cannot be decoupled from thermally activated doping.
Francesca Pallini   +15 more
wiley   +1 more source

Gut microbiota–derived short‐chain fatty acids regulate group 3 innate lymphoid cells in HCC

open access: yesHepatology, EarlyView., 2022
Abstract Background and Aims Type 3 innate lymphoid cells (ILC3s) are essential for host defense against infection and tissue homeostasis. However, their role in the development of HCC has not been adequately confirmed. In this study, we investigated the immunomodulatory role of short‐chain fatty acids (SCFAs) derived from intestinal microbiota in ILC3
Chupeng Hu   +11 more
wiley   +1 more source

Structural Origin of Spin‐Orbit Splitting of 1P Orbitals of Icosahedral Au13 Superatom Protected by Ligands

open access: yesAngewandte Chemie, EarlyView.
The spin‐orbit (SO) splitting of the superatomic 1P orbitals in thiolate‐protected Au13 superatoms were investigated. Cryogenic anion photoelectron spectroscopy and fully relativistic calculation including SO coupling revealed the 1P orbitals of the Au13 and Au@Ag12 superatomic cores undergo SO splitting, while not in the Ag13 core.
Shun Ito   +2 more
wiley   +2 more sources

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