Results 31 to 40 of about 8,220 (213)

Anion‐Controlled Structural Interconversion of Palladium Cages Enables Separations by Selective Guest Capture and Release

open access: yesAngewandte Chemie, EarlyView.
We report a pair of interconvertible palladium(II) cages assembled from an asymmetric ligand, whose switching is triggered by specific counter‐anions, tetrafluoroborate (BF4−) and bis(trifluoromethanesulfonyl)imide (NTf2−). Their complementary guest preferences enable orthogonal, multi‐cycle catch‐and‐release, exemplified by the selective purification ...
Zhe Li   +2 more
wiley   +2 more sources

High throughput synthesis of 2,5-substituted indoles using a titanium carbenoid bearing boronate functionality [PDF]

open access: yes, 2008
A titanium benzylidene complex bearing a boronate group converted resin-bound esters into enol ethers. Suzuki cross-coupling with aryl iodides followed by cleavage with acid completed the solid-phase synthesis of 2,5-disubstituted N-Boc-indoles.
Hartley, R.C.   +3 more
core   +1 more source

One‐Pot Amidation/C─H Halogenation by an Efficient Electrochemical Cascade

open access: yesAngewandte Chemie, EarlyView.
A sustainable electrochemical cascade enables the one‐pot synthesis of regioselectively halogenated N‐aryl amides from readily available amines and acyl halides under mild conditions. The method merges amidation and C─H halogenation in a single operational step, delivering broad substrate scope, high selectivity, and scalability, and provides an ...
Sudipta Ponra   +8 more
wiley   +2 more sources

Oxo-aglaiastatin-mediated inhibition of translation initiation [PDF]

open access: yes, 2019
We thank Dr. Elias George (McGill University) for the kind gift of Pgp-1-expressing HeLa cells. RIM was supported by a doctoral fellowship from the Cole Foundation.
Brown, Lauren E.   +9 more
core   +2 more sources

Modulators of hepatic lipoprotein metabolism identified in a search for small-molecule inducers of tribbles pseudokinase 1 expression. [PDF]

open access: yesPLoS ONE, 2015
Recent genome wide association studies have linked tribbles pseudokinase 1 (TRIB1) to the risk of coronary artery disease (CAD). Based on the observations that increased expression of TRIB1 reduces secretion of VLDL and is associated with lower plasma ...
Marek M Nagiec   +13 more
doaj   +1 more source

Biosynthetic pathways and related genes regulation of bioactive ingredients in mulberry leaves

open access: yesPlant Signaling & Behavior, 2023
Mulberry leaves are served not only as fodder for silkworms but also as potential functional food, exhibiting nutritional and medical benefits due to the complex and diverse constituents, including alkaloids, flavonoids, phenolic acids, and benzofurans ...
Na Lu   +6 more
doaj   +1 more source

Sulfur-containing benzofurans and α-pyrones from the mangrove-derived fungus Talaromyces sp. WHUF0341

open access: yesFrontiers in Marine Science, 2022
Two new sulfur-containing benzofurans, talarobenzofurans A and B (1 and 2), one new benzofuran talarobenzofuran C (3) and two new α-pyrones talaropyrones A and B (5 and 6), along with five known compounds eurothiocin A (4), nodulisporipyrone A (7 ...
Ruohan Zhang   +9 more
doaj   +1 more source

Synthesis of fluorinated oxygen- and sulfur-containing heteroaromatics [PDF]

open access: yes, 2017
Milk protein concentrate (79% protein) reconstituted at 13.5% (w/v) protein was heated (90 °C, 25 min, pH 7.2) with or without added calcium chloride.
Jones, David J.   +3 more
core   +1 more source

2-(2-Methoxyphenyl)-1-benzofuran [PDF]

open access: yesActa Crystallographica Section E Structure Reports Online, 2011
In the title compound, C(15)H(12)O(2), the dihedral angle between the aromatic ring systems is 16.67 (6)°. The methyl C atom is almost coplanar with its attached benzene ring [displacement = 0.020 (2) Å]. In the crystal, the mol-ecules are connected by weak C-H⋯O bonds and face-to-edge C-H⋯π inter-actions between the 2-meth-oxy-phenyl rings.
Michaela Pojarová   +4 more
openaire   +3 more sources

Chemical Constituents of Stems and Leaves of Tagetespatula L. and Its Fingerprint

open access: yesMolecules, 2019
Tagetespatula L. is a widely cultivated herbal medicinal plant in China and other countries. In this study, two new 2, 3-dihydrobenzofuran glucosides (1, 2) and fourteen known metabolites (3−16) were isolated from the stems and leaves of T. patula (
Yu-Meng Wang   +8 more
doaj   +1 more source

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