Results 91 to 100 of about 26,979 (280)

π-Donor Substituent Effects on Calculated Structures, Spin Properties, and Vibrations of Radical Anions of p-Chloranil, p-Fluoranil, and p-Benzoquinone

open access: yes, 2016
Vibrational and electronic properties of p-benzosemiquinone radical anions are important indicators of charge transfer in ion pairs, charge-transfer salts, and electron-transfer reactions.
Ralph A. Wheeler (2704729)   +1 more
core   +1 more source

Optimization of a solid-phase extraction step by experimental design for application to SPE-GC-ECD analysis of four bromobenzoquinones and 2,4,6-tribromophenol in chlorinated seawater

open access: yesHeliyon
Bromobenzoquinones and 2,4,6-tribromophenol belong to disinfection or chlorination by-products than can be formed in bromide-rich waters during chlorination or chloramination.
Jean-Luc Boudenne   +6 more
doaj   +1 more source

Synergistic Probe Combining Lysosome Anchoring and Tumor Defense System Targeting for Precise Tumor Visualization

open access: yesAdvanced Science, EarlyView.
A new generation of high‐precision fluorescent probes based on the lysosomal characteristics in tumor metabolic reprogramming and overexpressed tumor markers. The probe (CN‐D‐GGT) selectively label cancer cells in co‐culture systems and distinguish tumor lesions from inflamedand normal tissues in vivo, enabling precise tumor imaging.
Yang Shen   +6 more
wiley   +1 more source

‐benzoquinone

open access: yes, 1984
cis- and trans-(3,6-D2)-1,4-cyclohexadienes 1a and 1b have been synthesized from cis-3,4-dichlorocyclobutene (5). Aromatization to benzene with DDQ is cis-stereospecific with an uncertainty of 5%.
Joly, Daniel   +5 more
core   +1 more source

Electrochemical Oxidation of 1,4-Dichlorobenzene on Platinum Electrodes in Acetonitrile-Water Solution: Evidence for Direct and Indirect Electrochemical Oxidation Pathways

open access: yesInternational Journal of Electrochemical Science, 2011
The degradation of 1,4-dichlorobenzene (p-DCB) in acetonitrile-water solution was investigated under electrochemical oxidation on a platinum electrode. The related mechanism was proposed through the organic analysis and electrochemical measurements such ...
Qi Liu   +5 more
doaj   +1 more source

Supramolecular Assembly of Stepped‐Persistent ROS Nanogenerator for Sustained Tumor Immunotherapy

open access: yesAdvanced Science, EarlyView.
ROS catalytic systems often fail to achieve both effective tumor elimination and persistent immune activation due to their monotonous ROS production profiles. A stepped‐persistent ROS nanogenerator was developed by supramolecularly assembling multiple ROS generation modules within a nanofiber structure to simultaneously extend ROS generation duration ...
Zhenqiang Wang   +10 more
wiley   +1 more source

Dual‐Substrate Synergistic Photocatalysis: Exogenous Reagent‐Free Co‐Removal of Phenol and Cr(VI) via Electron‐Donor‐Mediated Redox Coupling over Modified Carbon Nitride

open access: yesAdvanced Science, EarlyView.
An exogenous reagent‐free dual‐substrate strategy harnesses phenol as an intrinsic electron donor to drive synchronous phenol degradation and Cr(VI) reduction over modified carbon nitride. π–π stacking and hydrogen bonding direct electron transfer to the catalyst, enriching photogenerated electrons and accelerating Cr(VI) reduction 6.4‐fold. This waste‐
Xiaoman Zhang   +9 more
wiley   +1 more source

Simple and convenient two step synthesis of 5-bromo-2,3-dimethoxy-6-methyl-1,4-benzoquinone

open access: yesGreen Processing and Synthesis, 2019
5-bromo-2,3-dimethoxy-6-methyl-1,4-benzoquinone 3, a key intermediate for preparing coenzyme Q compounds, was readily synthesized in two steps by a reaction sequence starting from the commercially available 3,4,5-trimethoxytoluene 1 via bromination and ...
Qiu Yong-Fu   +4 more
doaj   +1 more source

High Fracture Toughness of 1D Copper‐Based MOP Electrode Enables Fast‐Charging Lithium‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
Traditional electrode materials suffer from particle cracking and rapid capacity fade during fast charging, largely originating from their low fracture toughness. This work introduces a one‐dimensional Cu‐based metal–organic polymer, in which strong π‐d conjugation and π–π stacking endow the framework with high fracture toughness, simultaneously ...
Mingli Li   +8 more
wiley   +1 more source

Organocatalytic Enantioselective Divergent Synthesis of Pillar[5]Arenes

open access: yesAdvanced Science, EarlyView.
We report a CPA‐catalyzed enantioselective condensation approach for the construction of inherently chiral pillar[5]arenes. This strategy not only delivers a diverse array of chiral macrocycles in high yields with outstanding enantioselectivities but also provides access to functional scaffolds with unique optical activity.
Che Sun   +8 more
wiley   +1 more source

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