Results 61 to 70 of about 26,979 (280)

Comparative Transcriptome Analysis of Rhynchophorus ferrugineus (Coleoptera: Curculionidae) Reveals Potential Mechanisms Involved in the Toxication and Detoxification of the External Immune Compound p-Benzoquinone Present in Oral Secretions

open access: yesInsects
p-Benzoquinone (PBQ), a highly toxic compound, is the main active component in larval oral secretions of red palm weevil (RPW), Rhynchophorus ferrugineus, playing critical roles in external immunity and pathogen defense.
Juan Chen   +7 more
doaj   +1 more source

Catalytic, Asymmetric Inverse Electron Demand Hetero Diels-Alder Reactions of o-Benzoquinone Derivatives and Ketene Enolates

open access: yesCHIMIA, 2007
We present an array of [4+2] cycloaddition reactions between ketene enolates, catalytically derived from acid chlorides and cinchona alkaloid nucleophilic catalysts in the presence of stoichiometric base, and o-benzoquinone derivatives.
Daniel H. Paull   +4 more
doaj   +1 more source

Tyrosinase Driven‐Intracellular Polymerization of a Porphyrin Derivative Induced Immunogenic Death of Melanoma Cells and Strengthened Photodynamic Therapy

open access: yesAdvanced Science, EarlyView.
This study uses tyrosinase, which is highly expressed in melanoma, to drive porphyrins to polymerize and self‐assemble within tumor cells to form retented microstructures. This process induces immunogenic death and activates immune responses (M1 macrophages, dendritic cells, CD8+T cells), turning “cold” tumors into “hot” tumors.
Mian Tang   +9 more
wiley   +1 more source

Benzoquinone-Based Polyimide Derivatives as High-Capacity and Stable Organic Cathodes for Lithium-Ion Batteries

open access: yes, 2019
Multicarbonyl polyimide derivatives were synthesized by a facial condensation polymerization of dianhydrides with a new diamine monomer containing a benzoquinone unit that was prepared according to the Michael addition reaction. The ingenious combination
Zhaohu Ba (8180715)   +8 more
core   +1 more source

Simultaneous Wastewater‐to‐Hydrogen Upgrading via Mechanically Driven Piezocatalysis Over Ag‐ZnO Nanorods

open access: yesAdvanced Science, EarlyView.
A piezocatalytic strategy enables simultaneous wastewater purification and hydrogen generation by harnessing mechanical energy. Complementary piezo‐induced charges are selectively directed toward oxidation and reduction pathways, achieving efficient pollutant degradation and continuous H2 evolution.
Yiqing Wei   +8 more
wiley   +1 more source

Spatially Separated Redox Centers in One‐Dimensional Sp2‐Carbon Covalent Organic Frameworks Enable Synergistic Photocatalytic Palladium Recovery and Bisphenol A Mineralization

open access: yesAdvanced Science, EarlyView.
A one‐dimensional sp2‐carbon covalent organic framework with spatially segregated redox centers integrates a dual photosensitizing system and a cationic interface for synergistic photocatalysis. The material achieves exceptional palladium recovery (1749 mg g−1) and bisphenol A mineralization (0.1710 min−1) without sacrificial agents, demonstrating ...
Yi‐Ru Chen   +9 more
wiley   +1 more source

Synthesis of Angular Quinoid Heterocycles from 2-(2-Nitrovinyl)-1,4-benzoquinone

open access: yes, 2016
Reactions of 2-(2-nitrovinyl)-1,4-benzoquinone with furans, indoles, and endocyclic enol ethers form angular fused heterocyclic quinoid ring systems.
Brant L. Kedrowski (2431753)   +1 more
core   +1 more source

Synthesis and Antidepressant Evaluation of Three para-Benzoquinone Mono-oximes and Their Oxy Derivatives

open access: yesMolecules, 2006
A series of three para-benzoquinone mono-oximes and four oxy-derivatives were prepared and tested for their antidepressant properties. The (4E) oxime of 2-isopropyl-5- methyl-para-benzoquinone (4) and the corresponding 2-diethylamino-ethyl derivative (10)
Timothy John Brocksom   +3 more
doaj   +1 more source

Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage

open access: yesAdvanced Science, EarlyView.
A hexaanionic carboxyphenolate coordination framework, Ca2‐M‐THBPD (M = Mg, Ca, Ba), exhibits ligand‐centered enolate‐quinonoid redox activity enabling tunable, high‐voltage Ca2+ storage (3.5 V vs Ca2+/Ca) modulated by spectator cations. The amorphous structure accommodates reversible divalent‐ion insertion, contributing to enhanced cycling stability ...
Vasudeva Rao Bakuru   +12 more
wiley   +1 more source

New Hydrogen-Bonded Donor−Acceptor Pairs between Dipyridylacetylenes and 2,5-Dichloro-3,6-dihydroxy-1,4-benzoquinone

open access: yes, 2016
The crystalline donor−acceptor hydrogen-bonding complexes between 2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone (chloranilic acid) and dipyridylacetylenes (DPA) [2,2‘-DPA, 3,3‘-DPA, and 4,4‘-DPA] were prepared, and crystal structures were revealed by X-ray
Yoshiro Yamashita (1433242)   +2 more
core   +1 more source

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