Results 71 to 80 of about 17,647 (331)

Rh-Catalyzed Reactions of 1,4-Benzoquinones with Electrophiles:C-H Iodination, Bromination, and Phenylselenation [PDF]

open access: yes, 2016
Under Rh-catalyzed conditions, typically electrophilic 1,4-benzoquinones exhibit nucleophilic reactivity, such that exposure to appropriate electrophiles generates products of C-H iodination, bromination, and phenylselenation.
Bower, John F.   +2 more
core   +6 more sources

Tailoring the Properties of Functional Materials With N‐Oxides

open access: yesAdvanced Functional Materials, EarlyView.
The properties of materials bearing N‐oxide groups are often dominated by the polar N+─O− bond. It provides hydrophilicity, selective ion‐binding, electric conductivity, or antifouling properties. Many of the underlying mechanisms have only recently been discovered, and the interest in N‐oxide materials is rapidly growing.
Timo Friedrich   +5 more
wiley   +1 more source

Harmonizing the Pyrene and Ether Groups in Covalent Triazine Polymers for Highly Effective H2O2 Photosynthesis via One‐Step Two‐Electron Oxygen Reduction

open access: yesAdvanced Functional Materials, EarlyView.
The pyrene and ether groups are incorporated into the covalent triazine polymer (CTP) structure. The synergistic effect of the two functional groups endows CTP with better electron transfer, light absorption, and oxygen activation properties. An impressive apparent quantum yield (13.2% @420 nm) and a remarkable solar‐to‐chemical conversion efficiency ...
Chong Wang   +10 more
wiley   +1 more source

Stabilizing Cationic Palladium Single‐Atom Sites on Heteroatom‐Doped Carbon for Selective Hydrogen Peroxide Electrosynthesis

open access: yesAdvanced Functional Materials, EarlyView.
In this research, it is demonstrated that dual nitrogen and sulfur doping in hollow carbon spheres creates a tunable coordination environment that stabilizes cationic Pd single atoms as robust organometallic complexes, enabling high selectivity and stability for electrochemical hydrogen peroxide production under harsh acidic and peroxide‐rich ...
Guilherme V. Fortunato   +16 more
wiley   +1 more source

Synthesis of N-methoxy-N-methylaminocarbonyl-l, 4-benzoquinone: the First Quinone Carrying an N-methoxy-N-methylamino Group [PDF]

open access: yes, 1988
We report herein a four-step preparation of the title compound. Gentisic acid (1) was firstly converted into its diacetate (2) by treatment with acetic anhydride in the presence of concentrated sulfuric acid.
Ahmad, Faujan
core  

Enhanced coherent dynamics near a transition between neutral quantum-paraelectric and ionic ferroelectric phases in the quantum Blume-Emery-Griffiths model

open access: yes, 2008
Nonequilibrium dynamics are studied near the quantum phase transition point in the one-dimensional quantum Blume-Emery-Griffiths model. Its pseudo-spin component $ S^z $ represents an electric polarization, and $ (S^z)^2 $ corresponds to ionicity, in ...
K. Kimura, K. Nasu, Kenji Yonemitsu
core   +1 more source

Electrosynthesis of Bioactive Chemicals, From Ions to Pharmaceuticals

open access: yesAdvanced Functional Materials, EarlyView.
This review discusses recent advances in electrosynthesis for biomedical and pharmaceutical applications. It covers key electrochemical materials enabling precise delivery of ions and small molecules for cellular modulation and disease treatment, alongside catalytic systems for pharmaceutical synthesis.
Gwangbin Lee   +4 more
wiley   +1 more source

Antiplasmodial Natural Products

open access: yesMolecules, 2011
Malaria is a human infectious disease that is caused by four species of Plasmodium. It is responsible for more than 1 million deaths per year. Natural products contain a great variety of chemical structures and have been screened for antiplasmodial ...
Cláudio R. Nogueira, Lucia M. X. Lopes
doaj   +1 more source

Laser‐Induced Microfabrication of Carbon Nanostructure: Processing Mechanism and Application for Next‐Generation Battery Technology

open access: yesAdvanced Functional Materials, EarlyView.
The article reviews laser‐processed carbons from various precursors, processing mechanism and their application in advanced batteries. The laser process is chemical free, fast, and scalable, enabling improved battery performance and stability for Li, Na, and Zn battery technologies.
Sujit Deshmukh   +2 more
wiley   +1 more source

Synthesis and Spectral Analysis of 3,4,5-trichloro-6-(dibenzo[d,f][1,3]diazepin-5-yl)-[1,2]-benzoquinones

open access: yesE-Journal of Chemistry, 2011
Reaction of N1,N2-di-(4-methoxyphenyl)- or N1,N2-di-(4-hydroxyphenyl) -amidines (1a-d) with 3,4,5,6-tetrachloro-1,2-benzoquinone (2) in ethyl acetate at room temperature led to formation of new 3,4,5-trichloro-6-(2-hydroxy-6-methyldibenzo[d,f][1,3 ...
Mohsen A. M. Gomaa
doaj   +1 more source

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