A Noncovalent Click‐to‐Release Strategy to Control Bond Cleavage and Prodrug Activation
Angewandte Chemie, EarlyView.Extending the click‐to‐release concept beyond covalent ligation, we introduce a noncovalent click‐to‐release strategy based on cucurbituril‐adamantane (CB‐Ad) association. A supramolecular preassembly encapsulating a self‐immolative guest (SIG) is rationally designed to prevent premature release, while adding a high‐affinity Ad guest initiates the CB ...
Xuancheng Fu +9 more
wiley +2 more sources
Novel "green" catalysts for controlled ring-opening polymerization of lactide [PDF]
, 2010 Syntéza polylaktidu (PLA) polymerací za otevření kruhu cyklického monomeru (ROP) může být uskutečněna různými způsoby. Literatura uvádí více než 100 katalytických systémů, jejichž pomocí lze polylaktid a jiné biodegradabilní alifatické polyestery získat.
Surman, František
core
Advanced Science, EarlyView.Fe‐based magnetic nanocubes conjugated with TRPV1 antibodies (FeNCs‐TRPV1) are developed for the specific targeting of TRPV1 channels. Intraspinally injected FeNCs‐TRPV1 induces TRPV1 desensitization in rats exposed to repetitive and transient ACMF.
Xueying Cheng +15 more
wiley +1 more source
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
Angewandte Chemie, EarlyView.In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh +5 more
wiley +2 more sources
Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. [PDF]
, 2015 Alkyl oxalates are new bench-stable alcohol-activating groups for radical generation under visible light photoredox conditions. Using these precursors, the first net redox-neutral coupling of tertiary and secondary alcohols with electron-deficient ...
Jamison, Christopher R +4 more
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EFFECT OF BENZYL ALCOHOL (BA) ON RAT PLASMA LACTATE DEHYDROGENASE (LDH) [PDF]
, 1984 Philippe Samson +4 more
openalex +1 more source
Liquid-phase Alkylation of Toluene by Benzyl Alcohol over Micro-mesoporous Hierarchical Mordenite Zeolite [PDF]
, 2023 Rajib Bandyopadhyay, Hardik Koshti
openalex +1 more source
Expanding the Chemical Space of Cyclic Polyphthalaldehyde via Post‐Functionalization
Advanced Science, EarlyView.In this work, we developed a post‐functionalization approach to achieve water‐soluble cyclic polyphthalaldehyde (cPPA) polymers via click chemistry. ABSTRACT Cyclic polyphthalaldehydes (cPPAs) are hydrophobic cyclic polymers with stimuli‐responsive depolymerization property. The introduction of hydrophilic functionalities to cPPAs is challenging due to
Liting He +5 more
wiley +1 more source
Supported High‐Entropy Alloys for Electrooxidation of Benzyl Alcohol Assisted Water Electrolysis [PDF]
, 2023 Yan Wang +6 more
openalex +1 more source
Advanced Science, EarlyView.A polymer‐intercalated modulation assembly strategy was proposed to synthesize mesoporous single‐crystalline BiVO4 with tunable pore structure by co‐assembly of inorganic–organic composite through coordination bonds and hydrogen bonds. Thanks to single‐crystalline properties and mesoporous structure with vanadium vacancy microenvironment, the prepared ...
Wei Li +6 more
wiley +1 more source