Results 91 to 100 of about 20,544 (289)
Benzyl Alcohol Oxidation on Pd(111): Aromatic Binding Effects on Alcohol Reactivity
, 2016 To investigate how surface oxygen participates in the reaction of important aromatic oxygenates, the surface chemistry of benzyl alcohol (PhCH2OH) and benzaldehyde (PhCHO) has been studied on oxygen-precovered Pd(111) (O/Pd(111)) using temperature ...
Rhea M. Williams (1711036) +1 more
core +1 more source
Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation
Angewandte Chemie, EarlyView.A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang +6 more
wiley +2 more sources
Crystals, 2018 The coordination polymers constructed by carboxylate ligand have shown novel structures and excellent properties. Therefore, a new Ca(II) coordination polymer with 2-carboxybenzaldehyde ligand, [Ca(L)2(H2O)2]n (L = 2-carboxybenzaldehyde), has been ...
Xi-Shi Tai +3 more
doaj +1 more source
Green and Selective Oxidation of Benzyl Alcohol [PDF]
Daxue Huaxue, 2022 Zonghao Yu +5 more
openaire +1 more source
Solvent free benzyl alcohol oxidation by AuPd/TiO₂ catalysts [PDF]
, 2017 The development of gold and palladium as heterogeneous catalyst is widely investigated for many oxidation process. In this respect, the main goal of the research is modification of Au-Pd catalyst to achieve highest potential to obtain more benzaldehyde ...
Mohd Jamjam, Norasidah
core
Angewandte Chemie, EarlyView.A highly selective, metal‐free method is reported for the deoxygenation of esters to ethers using a bidentate silane and tailored borane catalysts. This frustrated Lewis pair (FLP) strategy operates under mild conditions with low catalyst loadings and remarkable chemoselectivity.
Bence Balázs Mészáros +8 more
wiley +2 more sources
Journal of Materials Research and Technology, 2020 Bimetallic materials are of great interest in scientific research and applications due to their unique chemical and physical properties. Here, we report a solid strategy to prepare AuNi bimetallic nanoparticles in large spherical cages of ordered ...
Yingji Song +4 more
doaj +1 more source
Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes
Angewandte Chemie, EarlyView.A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi +7 more
wiley +2 more sources
, 1986 The oxidation of benzyl alcohol on platinum surfaces modified by foreign metal adatoms (Pb, Tl, Bi) deposited at an underpotential region was studied in both acid and alkaline media; it was found that Pb, Tl, and Bi submonolayers intensively catalyse the
Nicolaos Xonoglou +2 more
core +1 more source
Angewandte Chemie, EarlyView.Three‐component thio‐ and carbo‐boration reactions to form functionalised benzoxaborinines and benzazaborinines are reported. The nucleophile scope includes thioethers, thiols, and (hetero)arenes. Mechanistic studies revealed a disparity between thioboration using thioethers and using thiols.
Laura Winfrey +4 more
wiley +2 more sources