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Mavacamten and atrial fibrillation: assessing the risk through FAERS and meta-analysis. [PDF]
Ding L, Liao X, Yang Y, Chen C, Xiao J.
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Hydroalkylation of Styrenes with Benzylamines by Potassium Hydride
Helvetica Chimica Acta, 2021AbstractA method for the synthesis of 1,3‐diarylpropylamines through hydroalkylation of styrenes with benzylamines by potassium hydride has been developed. The protocol is initiated by solvothermal treatment of benzylamines with KH at 100 °C to generate deprotonated anionic species, which undergo selective C‐alkylation with arylalkenes at 0 °C to ...
Kohei Watanabe +2 more
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Sustainable Production of Benzylamines from Lignin
Angewandte Chemie - International Edition, 2021AbstractCatalytic conversion of lignin into heteroatom functionalized chemicals is of great importance to bring the biorefinery concept into reality. Herein, a new strategy was designed for direct transformation of lignin β‐O‐4 model compounds into benzylamines and phenols in moderate to excellent yields in the presence of organic amines.
Changzhi Li, Tenglong Guo, Tao Zhang
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Mass spectrometry of benzylamines and benzylamine derivatives
Organic Mass Spectrometry, 1972AbstractThe mass spectra of benzylamine, N‐ethylbenzylamine, N,N‐dimethylbenzylamine, p‐methoxybenzylamine and 4‐hydroxy‐3‐methoxybenzylamine, and their acetamide and trimethyl‐ silyl (TMS) derivatives have been recorded. Low and high resolution spectroscopy were employed in conjunction with ion kinetic energy (IKE) determinations to establish the ...
M. W. Couch, C. M. Williams
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Oxidative deamination of benzylamine by glycoxidation
Bioorganic & Medicinal Chemistry, 2003In the present study, model reactions for the oxidative deamination by glycoxidation using benzylamine were undertaken to elucidate the detail of the reaction. Glucose, 3-deoxyglucosone (3-DG), and methylglyoxal (MG) oxidatively deaminated benzylamine to benzaldehyde in the presence of Cu(2+) at a physiological pH and temperature but not glyoxal.
Mitsugu, Akagawa +2 more
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The Catalytic Hydrogenolysis of Benzylamine Derivatives
Tetrahedron, 1973Abstract The hydrogenolysis of optically active ethyl 2-amino-2-phenylpropionate ( I ), its N-methyl ( II ), and N,N-dimethyl ( III ) derivatives was studied using Raney Ni and Pd as the catalysts. The Raney Ni catalysed hydrogenolysis of II and III , as well as the reaction catalysed by Pd, occurred predominantly with inversion of configuration ...
Y. Sugi, S. Mitsui
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The enthalpy of formation of benzylamine
The Journal of Chemical Thermodynamics, 1977Abstract The enthalpy of combustion of liquid benzylamine has been measured using a static combustion calorimeter and the enthalpy of formation: ΔH f o (C 7 H 9 N, 1, 298.15 K) = (8.18 ± 0.41) kcal th mol −1 has been derived. The enthalpy of formation of the gas: ΔH f o (C 7 H 9 N, g, 298.15 K) = (20.98 ± 0.65) kcal th mol −1 has been ...
A.S. Carson, P.G. Laye, M. Yürekli̇
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Tautomerism in Salicylidene Benzylamine
Spectroscopy Letters, 1992Abstract The UV spectra of substituted salicylidene benzylamine schiff bases were studied in four solvents. It was found that substituents which increase the electronic effect and not the steric compression effect in these compounds increase the percentage of the keto form. The intensity (i.e. % keto) of the keto band which occurs at > 400 nm in the UV
Fadhil S. Kamounah +2 more
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Oxidation of Benzylamines to Amides
Synthetic Communications, 1997Abstract A convenient method for the conversion of tertiary benzylamines to benzamides by phase transfer oxidation is described. Yields are good. Regioselectivities are reported.
J. Hodge Markgraf +2 more
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Reactions of Benzylamine with Sulfur
Canadian Journal of Chemistry, 1971A five-step sequence has been established for the room temperature reaction of sulfur with benzylamine. Benzylamine polysulfides and benzylidenimine polysulfides occur as interconverting intermediates in this system. The final products are benzylammonium polysulfides, ammonia, and N-benzylidene benzylamine.
Yukihiko Sasaki, Fredric P. Olsen
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