Results 111 to 120 of about 3,554 (196)
Synthesis of a Novel Amine‐Based Curing Agent for Epoxy Resins Derived From Vanillin
The four‐step synthesis of a new bio‐based amine hardener is described starting from vanillin as a bio‐based compound. The hardener ADBA was utilized to cure DGEBA and the resulting T g,tanδmax was determined via DMA. Compared to other bio‐based curing agents, our curing agent is obtainable in a high yield and leads to a superior T g of 135°C ...
Bastian Hahn +3 more
wiley +1 more source
Rh(III)‐Catalyzed Synthesis of Multisubstituted Isoquinolines from Benzylamines and Diazo Compounds
International audienceMultisubstituted isoquinolines have been prepared by Rh(III)-catalyzed cyclization of benzylamines with diazo compounds via aryl C-H bond activation using molecular oxygen from air as an oxidant.
Xiuling Cui +11 more
core +1 more source
An efficient and novel electrochemical oxidative tandem cyclization of aryl ketones and benzylamines for the synthesis of 1,2,4-trisubstituted-(1H)-imidazoles has been developed under metal- and oxidant-free conditions.
Kun Liu +15 more
core +1 more source
Synthesis and Fluorescence Profiling of Naphthylamine Analogs
N‐phenyl‐1‐naphthylamine (NPN) has been historically used as a probe to monitor gram‐negative bacterial outer membrane permeabilization, fluorescing only in hydrophobic environments. Herein, a 95‐membered naphthylamine library was synthesized to explore structure–fluorescence relationships, informed by density functional theory studies.
Cole M. Friederichs +6 more
wiley +1 more source
Starting from carboxylic acids and Selectfluor‐derivatives, functionalized diazabicyclooctanes can be obtained via a novel Polonovski‐type rearrangement proceeding under mild reaction conditions. Besides their use in organic synthesis the unique structure and reactivity of the rearrangement products enables applications in medicinal chemistry ...
Jakob Kuhn +5 more
wiley +1 more source
Base and solvent dependency of an oxidative retro-alkylation of secondary and tertiary benzylamines
An iodine and caesium carbonate amine oxidation protocol is described. Non-branched secondary benzylamines were cleanly oxidised to aldimines that could be isolated without the need for chromatography.
Feula, A., Fossey, J.S.
core +1 more source
A palladium-catalyzed C–H carbonylation of benzylamines for the synthesis of isoindolinone scaffolds has been developed. This protocol is conducted under gas-free conditions by using benzene-1,3,5-triyl triformate (TFBen) as a convenient CO surrogate ...
Xiao-Feng Wu (1617313) +4 more
core +1 more source
Visible‐Light‐Initiated, Nickel‐Catalyzed Aminocarbonylation of Alkynyl Iodides to 2‐Ynamides
Visible light initiates a nickel‐catalyzed aminocarbonylation of alkynyl iodides, enabling the synthesis of 2‐ynamides under low carbon monoxide pressure. The method operates under mild conditions, tolerates a broad substrate scope, and proceeds through a light‐triggered nickel(I)/nickel(III) carbonylative pathway.
Michael Weiser +5 more
wiley +1 more source
Benzylamines: synthesis and evaluation of antimycobacterial properties
The synthesis of benzylamines with various N-alkyl chains and substituents in the aromatic system as well as their evaluation on Mycobacterium tuberculosis H 37 Ra are described.
Angerer, Erwin von +3 more
core +1 more source
We demonstrate programmable structural symmetry and emission in benzylammonium‐based low‐dimensional hybrid perovskites. Continuous shaking transforms orthorhombic platelets into a lower‐symmetry monoclinic phase with broadband emission, whereas thermal activation drives the reverse pathways toward a higher‐symmetry configuration resembling the ...
Luiz G. Bonato +7 more
wiley +1 more source

