Visible Light or Brønsted Acid Promoted Oxygenation of a PdBn(NNP(O)) Complex
A benzylpalladium complex with a tridentate NNP ligand containing 2,2′‐bipyridine and a phosphoryl moiety [PdBn(MeNNP(O))] reacted readily with O2 to afford an O2‐inserted complex. The insertion was accelerated using ambient light. By contrast, the reaction with O2 under blue LED irradiation afforded PhCHO as the major oxygenated product.
Risa Shibai +3 more
wiley +1 more source
Application of Silibinin Oleate as a Nutraceutical Antioxidant for Improving the Quality of Sunflower Oil. [PDF]
Dehelean CA +10 more
europepmc +1 more source
Aziridinierung eines einzelnen Kohlenstoffatoms in Alkenen mittels Energietransferkatalyse
Im Gegensatz zur traditionellen Alken‐Aziridinierung über (formalen) Nitren‐Transfer berichten wir hier über eine Strategie zur intermolekularen Aziridinierung eines einzelnen Alken‐Kohlenstoffatoms bei zusätzlicher Funktionalisierung der anderen Position. Durch Energietransfer‐ (EnT‐)Katalyse werden Alkenylboronate und ‐silane in reaktive Intermediate
Fritz Paulus +7 more
wiley +1 more source
Enhancing the quality and oxidative stability of sunflower oil during thermal treatment with an ultrasound-extracted pomegranate flower (<i>Punica granatum</i> L.) extract. [PDF]
Ali RFM, Alayouni R, El-Anany AM.
europepmc +1 more source
Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis
Contrary to traditional alkene aziridination via (formal) nitrene transfer, we herein report a strategy that achieves intermolecular aziridination of a single alkene carbon atom and installs an additional group at the other. Enabled by metal‐free energy transfer (EnT) catalysis, alkenyl boronates and silanes are transformed into reactive intermediates ...
Fritz Paulus +7 more
wiley +1 more source
Antioxidant Capacity Alterations in Bangladeshi Underutilized Fruits: InsightsFrom In Vitro Gastrointestinal Digestion Studies. [PDF]
Alam M +5 more
europepmc +1 more source
Visible light activates β‐aryl α,β‐unsaturated acylsilanes to form indenols without catalysts or metals. A stepwise photochemical cascade reorganizes simple precursors through isomerization, rearrangement, and ring formation. The process highlights sustainable reaction design while showcasing the synthetic power of acylsilane photochemistry and the ...
Adrián Álvarez +4 more
wiley +1 more source
Break-through amplified spontaneous emission with ultra-low threshold in perovskite via synergetic moisture and BHT dual strategies. [PDF]
Zhang D +13 more
europepmc +1 more source
Graphical overview of the effects of the high‐fat, high‐sucrose (HFHS) diet regime and 2‐week cannabigerol (CBG) treatment on the intramuscular long‐chain fatty acids (LCFAs) trafficking and lipid metabolism, with subsequent implications for mitochondrial cardiolipin (CL) composition in the red gastrocnemius muscle.
Patrycja Bielawiec +3 more
wiley +1 more source
14C-Labelling of Butylated Hydroxytoluene (BHT)
YOSHITAKE, Akira +2 more
openaire +3 more sources

