The Mechanism of Visible‐Light Photochemical Rearrangements of Conjugated Amide Enolates
Visible light irradiation of extended enolates of N‐benzylamides leads to homolytic C─N Bond cleavage, generating a biradical. Computational and mechanistic studies suggest rapid radical recombination within a solvent cage to give either ring‐expanded or rearranged products. ABSTRACT Deprotonation of conjugated amides forms colored solutions of lithium
James Mortimer +3 more
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Demographics, Injury Patterns, Injury Severity and Injury Predictors in Children with Non-Fatal Injuries Due to Road Traffic Injuries: An Analysis by Mode of Transportation. [PDF]
Loder RT, Koch H.
europepmc +1 more source
N‐Sulfonyl Azalevoglucosan: A Versatile Platform for the Synthesis of Polysubstituted Piperidines
Gain by strain: The synthesis of a levoglucosan analog, in which the pyranose oxygen has been replaced by a nitrogen, allows navigation on the piperidine ring to iteratively install functional groups at C1, C2, C3, C4, and C6 positions using simple experimental protocols with minimal protecting group manipulation.
Dylan Yorga +6 more
wiley +1 more source
Feasibility of a noninvasive photoplethysmography-based wearable chest patch for cardiac output assessment during exercise compared with thermodilution right heart catheterization. [PDF]
Stücker B +7 more
europepmc +1 more source
Effect of Mandatory Bicycle Helmet Legislation on Helmet Use and Injury Outcomes: A Propensity Score-Matched Analysis Using Decision Tree and Segmented Regression. [PDF]
Park H +5 more
europepmc +1 more source
Clinical severity of dry eye disease and its association with tear film inflammatory biomarkers among adults in Northern Ethiopia: A multicentre cross-sectional study. [PDF]
Gudayneh YA +7 more
europepmc +1 more source
Effects of bicycle infrastructure interventions on physical activity in the general population: rapid review. [PDF]
Stähler L +5 more
europepmc +1 more source
Exploring the psychological and physiological effects of a virtual reality-based bicycle exercise in hemodialysis patients: a randomized controlled trial. [PDF]
Hu J +6 more
europepmc +1 more source
Cycling Interventions Enhance Executive Function in Children with Autism via Heart Rate Variability Mediation: A Randomized Controlled Trial. [PDF]
Tse ACY +7 more
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