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Merging Ketyl Radical Chemistry and Allylboration via Strain Release: One-Pot Multicomponent Access to Sterically Congested Ketone-Functionalized Organoborons. [PDF]

Org Lett
Mini A, Vyas H, Gangani AJ, Melada M, Shin A, Sharma A.   +5 more
europepmc   +1 more source

Comparative LCMS2 Analysis of Synthetic Ether- and Ester-Linked Polyacids Refines Structural Boundaries for Small Molecules in Dissolved Organic Matter. [PDF]

Environ Sci Technol
Flygare AD, Moodie LWK, Hawkes JA, Craig AJ.   +3 more
europepmc   +1 more source

A General Metallaphotoredox Platform for <i>N</i>-Alkylated Sulfoximines as Bioisosteric Building Blocks. [PDF]

J Am Chem Soc
Großkopf JJ, Morgan DC, Clarke AK, MacMillan DWC.   +3 more
europepmc   +1 more source

Scientific Opinion of the Panel on Food Additives, Flavourings, Pro cessing Aids and Materials in Contact with Food on a request from Commission on Flavouring Group Evaluation 87, (FGE.87) bicyclic secondary alcohols, ketones and related esters:EFSA-Q-2008-071

, 2008
openaire   +1 more source

Fused-Linked and Spiro-Linked N-Containing Heterocycles. [PDF]

Int J Mol Sci
Moskalik MY, Shainyan BA.
europepmc   +1 more source

Catalytic Oxidative Ligand Transfer of Rh-Carbynoids and Alkyl Iodides. [PDF]

J Am Chem Soc
Esteve Guasch J, Pal D, Suero MG.
europepmc   +1 more source

Dynamic Reactivity: Reversible Reaction of a Phosphinine-Borane Adduct With Water and Double Hydrophosphination. [PDF]

Chemistry
Frank S, Horváth Á, Horváth JB, Interdonato C, Ernst MJ, Kumar P, Benkő Z, Müller C.   +7 more
europepmc   +1 more source

Enantioselective synthesis of allylic boronates bearing a stereodefined (<i>E</i>)-alkenyl chloride by Cu-catalyzed borylation of allylic <i>gem</i>-dichlorides.

Org Chem Front
Chaves-Pouso A, Álvarez-Constantino AM, Gómez-Roibás P, Fañanás-Mastral M.   +3 more
europepmc   +1 more source

Kinetic resolution of secondary alcohols using proline-derived bicyclic iminium salts

Tetrahedron Letters, 1997
The proline-derived bicyclic iminium salt 3 can be used to bring about kinetic resolution in its reaction with salts of secondary alcohols to give the corresponding methyl sulfides. Reaction proceeds most efficiently with sodium 1-phenylethoxide in toluene at RT where either 3 or the bezyl salt 14 give e.e.s of 21–25% and changing the heteroatoms ...
R Alan Aitken, Shaun T E Mesher
exaly   +3 more sources

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Mechanism of oxidation of secondary alcohols by bromine—oxidation of bicyclic secondary alcohols

Proceedings of the Indian Academy of Sciences - Section A, 1968
The kinetics of the bromine oxidation of borneol, isoborneol,α-norborneol andβ-norborneol have been investigated in order to find out whether the oxidation is sensitive to the configuration of the alcohol. There is a definite and considerable variation in rate which is shown to arise from stereochemical consequences.
N Venkatasubramanian, Venkatasubramanian N   +1 more
exaly   +2 more sources