The Stabilization of High‐Nitrogen Systems: 10 Catenated Nitrogen Chain
Improving the understanding of high‐nitrogen materials. ABSTRACT High‐nitrogen materials have attracted intense interest in recent decades due to their unique chemical, physical, and biological properties. Stabilizing high‐nitrogen materials is often challenging as they become more unstable with increasing nitrogen catenation and nitrogen mass ...
Nicholas F. Scherschel +3 more
wiley +1 more source
Metabolic biochemical models of N<sub>2</sub> fixation for sulfide oxidizers, methanogens, and methanotrophs. [PDF]
Gao M +11 more
europepmc +1 more source
High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao +8 more
wiley +1 more source
Enhancement of Nitrogenase Activity in Recombinant Escherichia coli by Replacing Upstream Region of nif Operon from Paenibacillus Species. [PDF]
Honda Y +4 more
europepmc +1 more source
Calix[4]arene Design for Enhanced Carbon Capture via Topological Learning
ABSTRACT Solid direct air capture (S‐DAC) technologies have the potential to remove pre‐existing CO2 from the atmosphere by taking advantage of hydrophobic materials that will retain CO2 through physisorption and separating it from the abundant water molecules. Calix[n]arenes are highly tunable and versatile complexes with inherent hydrophobic cavities,
Jeffrey A. Laub +1 more
wiley +1 more source
Resurrected nitrogenases recapitulate canonical N-isotope biosignatures over two billion years. [PDF]
Rucker HR +6 more
europepmc +1 more source
Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel +5 more
wiley +1 more source
One‐pot synthesis of asymmetric organic carbonates from CO2, methanol, and other alcohols was demonstrated in the presence of CeO2 catalyst and 2‐cyanopyridine dehydrant. This reaction proceeded through two reaction pathways—direct route via cross‐carboxylation and indirect route via production of DMC and subsequent transesterification.
Yuan Li +4 more
wiley +1 more source
Engineering Plasma-Liquid Microdischarge Systems for Direct N<sub>2</sub>‑to-NH<sub>3</sub> Conversion at Ambient Conditions. [PDF]
Torre MF +8 more
europepmc +1 more source
Sodium alginate was modified with EDC/NHS for the immobilization of Yacon peel peroxidase, resulting in a novel biocatalyst for the oxidation of 2,4‐dichlorophenol. Abstract Yacon (Smallanthus sonchifolius) roots are emerging as an alternative source of peroxidase. This study aimed to extract, immobilize, and characterize the peroxidase from Yacon peel,
Mariana Gomes Oliveira +4 more
wiley +1 more source

