Results 201 to 210 of about 124,422 (325)

The Stabilization of High‐Nitrogen Systems: 10 Catenated Nitrogen Chain

open access: yesChemistry – A European Journal, EarlyView.
Improving the understanding of high‐nitrogen materials. ABSTRACT High‐nitrogen materials have attracted intense interest in recent decades due to their unique chemical, physical, and biological properties. Stabilizing high‐nitrogen materials is often challenging as they become more unstable with increasing nitrogen catenation and nitrogen mass ...
Nicholas F. Scherschel   +3 more
wiley   +1 more source

Metabolic biochemical models of N<sub>2</sub> fixation for sulfide oxidizers, methanogens, and methanotrophs. [PDF]

open access: yesmSystems
Gao M   +11 more
europepmc   +1 more source

High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao   +8 more
wiley   +1 more source

Calix[4]arene Design for Enhanced Carbon Capture via Topological Learning

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Solid direct air capture (S‐DAC) technologies have the potential to remove pre‐existing CO2 from the atmosphere by taking advantage of hydrophobic materials that will retain CO2 through physisorption and separating it from the abundant water molecules. Calix[n]arenes are highly tunable and versatile complexes with inherent hydrophobic cavities,
Jeffrey A. Laub   +1 more
wiley   +1 more source

Resurrected nitrogenases recapitulate canonical N-isotope biosignatures over two billion years. [PDF]

open access: yesNat Commun
Rucker HR   +6 more
europepmc   +1 more source

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

open access: yesChemistry – A European Journal, EarlyView.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel   +5 more
wiley   +1 more source

Cross‐Carboxylation of Methanol and Other Alcohols With CO2 Into Asymmetric Alkyl Methyl Carbonates Over a CeO2 Catalyst

open access: yesChemistry – A European Journal, EarlyView.
One‐pot synthesis of asymmetric organic carbonates from CO2, methanol, and other alcohols was demonstrated in the presence of CeO2 catalyst and 2‐cyanopyridine dehydrant. This reaction proceeded through two reaction pathways—direct route via cross‐carboxylation and indirect route via production of DMC and subsequent transesterification.
Yuan Li   +4 more
wiley   +1 more source

Engineering Plasma-Liquid Microdischarge Systems for Direct N<sub>2</sub>‑to-NH<sub>3</sub> Conversion at Ambient Conditions. [PDF]

open access: yesACS Sustain Chem Eng
Torre MF   +8 more
europepmc   +1 more source

Valorization of Yacon (Smallanthus sonchifolius) peel for peroxidase production and its immobilization on alginate beads for 2,4‐dichlorophenol bioconversion

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Sodium alginate was modified with EDC/NHS for the immobilization of Yacon peel peroxidase, resulting in a novel biocatalyst for the oxidation of 2,4‐dichlorophenol. Abstract Yacon (Smallanthus sonchifolius) roots are emerging as an alternative source of peroxidase. This study aimed to extract, immobilize, and characterize the peroxidase from Yacon peel,
Mariana Gomes Oliveira   +4 more
wiley   +1 more source

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