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Chapter 4 Bisindole Alkaloids

2006
Publisher Summary This chapter provides an overview on bisindole alkaloids. The indole–indole and tryptamine–tryptamine type, and related alkaloids are discussed. Tryptamine–tryptamine type with an additional monoterpene unit and related alkaloids are briefly discussed.
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The IBOGA alkaloids and their role as precursors of anti-neoplastic bisindole catharanthus alkaloids

ChemInform, 2002
AbstractFor Abstract see ChemInform Abstract in Full Text.
Richard J, Sundberg, Stanton Q, Smith
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Melosuavine I, an apoptosis-inducing bisindole alkaloid from Melodinus suaveolens

Fitoterapia, 2019
A new bisindole alkaloid, melosuavine I (1) possessing an aspidosperma-aspidosperma dimeric skeleton, was isolated from the leaves of Melodinus suaveolens. The structure with absolute configuration of 1 was elucidated by a combination of MS, NMR and computational methods.
Zhong-Ying Fang, Yi-Dan Ren, Si-Yu Du, Miao Zhang, Yun-Shan Wang, Lei Fang, Hua Zhang   +6 more
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Ceridimine: a novel type of bisindole monoterpene alkaloid

Journal of the Chemical Society, Chemical Communications, 1986
The structure determination and synthesis of ceridimine (1), a novel type of bisindole monoterpene alkaloid isolated from Pagiantha cerifera(Apocynaceae), are reported.
Genevi�ve Baudouin, Fran�ois Tillequin, Maryse Bert, Michel Koch   +3 more
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Aspidosperma–aspidosperma-type bisindole alkaloids from Voacanga africana

Tetrahedron, 2013
Abstract Four new aspidosperma–aspidosperma-type bisindole alkaloids 1–4 were isolated from the seeds and root bark of Voacanga africana (Apocynaceae) and their structures were determined by spectroscopic analysis. Among them, voacandimine A (2) featured a linkage mode new to dimeric monoterpenoid indole alkaloids.
Mariko Kitajima, Masumi Iwai, Noriyuki Kogure, Ruri Kikura-Hanajiri, Yukihiro Goda, Hiromitsu Takayama   +5 more
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Vincazalidine A, a unique bisindole alkaloid from Catharanthus roseus

Journal of Natural Medicines
A new dimeric indole alkaloid, vincazalidine A consisting of an aspidosperma type and a modified iboga type with 1-azatricyclo ring system consisting of one azepane and two piperidine rings coupled with an oxazolidine ring was isolated from Catharanthus roseus, and the structure including absolute stereochemistry was elucidated on the basis of ...
Yusuke, Hirasawa, Ayaka, Kase, Akie, Okamoto, Keigo, Suzuki, Mizuki, Hiroki, Toshio, Kaneda, Nahoko, Uchiyama, Hiroshi, Morita   +7 more
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Obovatine, a New Bisindole Alkaloid from Stemmadenia obovata

Journal of Natural Products, 1995
The stem bark of the Panamanian plant Stemmademia obovata has afforded a new ibogaine-type alkaloid, obovamine (1), whose structure was determined by a combination of spectral interpretation and ch...
E. Valencia, A. Madinaveitia, J. Bermejo, A. G. Gonzalez   +3 more
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Conodusarine, a New Biologically Active Bisindole Alkaloid from Tabernaemontana divaricata

HETEROCYCLES, 2004
A new bisindole alkaloid of the vobasine-iboga type, conodusarine, was isolated from the stem-bark extract of Tabernaemontana divaricata and the structure established by spectroscopic analysis.
Toh‐Seok Kam, Huey‐Shen Pang
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Cathagines A–D, new bisindole alkaloids from Catharanthus roseus

Journal of Natural Medicines
Four new bisindole alkaloids, cathagines A (1)-D (4) consisting of an aspidosperma and the fused tetracyclic 3-spirooxindole derived from an iboga type skeleton were isolated from the whole plant of Catharanthus roseus. The structures including absolute stereochemistry were elucidated on the basis of 2D NMR data and CD spectra.
Yusuke, Hirasawa, Chiaki, Kasagi, Erika, Koyama, Hitomi, Myojin, Takahiro, Tougan, Toshihiro, Horii, Nahoko, Uchiyama, Toshio, Kaneda, Hiroshi, Morita   +8 more
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Insecticidal bisindole alkaloids from leaves of Tabernaemontana divaricata 'Dwaft'

Phytochemistry
Six undescribed bisindole alkaloids, namely taberdisines A-F (1-6), were isolated from the leaves of Tabernaemontana divaricata 'Dwaft'. Among them, alkaloids 1 and 2 were the first examples of strychnos-iboga type alkaloid with both C-C linkage patterns. Alkaloid 3, a new type of aspidosperma-iboga with a furan-ring, as well as other three undescribed
Jing Chen, Sumet Kongkiatpaiboon, Xiang-Hai Cai   +2 more
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