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Synthesis of Borane Complexes: From Small Borane Molecules to Polyhedral Boranes
He huaxue yu fangshe huaxue, 2023 Borane is a class of boron compounds, including active small borane molecules and relative stable polyhedral borane compounds, and has widely applied in energy storage, material science, and pharmaceutical medicine, especially as promising boron carriers
JING Yi +4 more
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Catalytic asymmetric constructions of nitrogen, boron and carbon continuous stereogenic centers [PDF]
Nature CommunicationsPrecise construction of molecular chirality is a longstanding scientific challenge in synthetic chemistry. Although methods to enantioselectively assemble consecutive carbon stereocenters are abundant, courses to establish enriched continuous ...
Guan Zhang +6 more
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Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes [PDF]
Molecules, 2020 Thermodynamic hydricity (HDAMeCN) determined as Gibbs free energy (ΔG°[H]−) of the H− detachment reaction in acetonitrile (MeCN) was assessed for 144 small borane clusters (up to 5 boron atoms), polyhedral closo-boranes dianions [BnHn]2−, and their ...
Igor E. Golub +5 more
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Interaction of Laguerre–Gaussian laser pulses with borane targets of different hydrogen–boron ratio [PDF]
Scientific ReportsWe study the interaction of high-intensity Laguerre-Gaussian laser pulses with hydrogen–boron compounds targets using 3D particle-in-cell simulations.
Lars Reichwein +2 more
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A Short Chronological Review on the Syntheses of Amine-Boranes [PDF]
Chemical Review and Letters, 2020 Since their discovery by Burg and Schlesinger in 1937, amine-boranes have enjoyed a rich preparative history and have experienced reinvigorated interest as valuable compounds.
Daniel Reddy
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Isolable Diaminophosphide Boranes [PDF]
Chemistry – A European Journal, 2020 AbstractMetalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and selective access route to a range of metal diaminophosphide boranes M[(R2N)2P(BH3)] (M=Li, Na, K; R=alkyl, aryl) with acyclic or heterocyclic molecular backbones, whereas reduction of a chlorodiaminophosphine borane gave less satisfactory results.
Markus Blum +5 more
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Acta Crystallographica Section E Structure Reports Online, 2009 The title compound, C3H12BN, was solved using data collected from a multiple crystal (note incomplete data shell). The cell packing is dominated by bifurcated attractive N—Hδ+...δ−H—B interactions.
Gainsford, Graeme J., Bowden, Mark E.
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Nucleophilic Substitution Reactions in the [B3H8]− Anion in the Presence of Lewis Acids
Molecules, 2022 As a result of our study on the interaction between the octahydrotriborate anion with nucleophiles (Nu = THF, Ph3P, Ph2P-(CH2)2-PPh2 (dppe), Ph3As, Et3N, PhNH2, C5H5N, CH3CN, Ph2CHCN)) in the presence of a wide range of Lewis acids (Ti(IV), Hf(IV), Zr(IV)
Alexandra T. Shulyak +8 more
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Hexafluoroisopropylboranes and -Borates
Inorganics, 2023 Novel hexafluoroisopropylboranes (CF3)(CF2H)CFBH2·L and -borate anions [(CF3)(CF2H)CFBH2X]− with Lewis basic heterocyclic ligands L and the anionic substituents X = F− and CN− were obtained.
Ludwig Zapf, Maik Finze
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Molecules, 2023 Cyclopropylamine borane C3H5NH2BH3 (C3AB), 2-ethyl-1-hexylamine borane CH3(CH2)3CH(C2H5)CH2NH2BH3 (C2C6AB) and didodecylamine borane (C12H25)2NHBH3 ((C12)2AB) are three new amine borane adducts (ABAs).
Kevin Turani-I-Belloto +6 more
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