Transmission of Radio‐Frequency Waves and Nuclear Magnetic Resonance in Lanthanum Superhydrides
Advanced Science, EarlyView.1H NMR and radio‐frequency transmission measurements of lanthanum superhydrides at 165 GPa reveals a transition at 260–280 K by a strong suppression of the signal intensity, significant changes in NMR spectra, including a dramatic decrease of the relaxation rate 1/T1T, and pronounced shielding effect, which may have a superconducting nature.
Dmitrii V. Semenok +8 more
wiley +1 more source
Tris(pentafluorophenyl)borane and beyond: modern advances in borylation chemistry [PDF]
, 2017 As main-group chemistry, in particular boron chemistry, has expanded and developed over the past 20 years, one reagent has risen to prominence as well.
James R. Lawson +3 more
core +2 more sources
Fabrication of Composite Cathode for All‐Solid‐State Sodium Batteries
Advanced Energy Materials, EarlyView.The design of composite cathodes for all‐solid‐state sodium batteries must address three critical challenges—interfacial side reactions, interfacial delamination, and highly tortuous transport pathways. This work outlines structural and interfacial strategies to optimize ion transport and mechanical stability, enabling durable, and high‐performance ...
Gaoming Sun +6 more
wiley +1 more source
Role of Li_2B_(12)H_(12) for the Formation and Decomposition of LiBH_4 [PDF]
, 2010 By in situ X-ray diffraction (XRD) and nuclear magnetic resonance (NMR) spectroscopy, the role of Li_2B_(12)H_(12) for the sorption of LiBH_4 is analyzed.
Friedrichs, O. +3 more
core
From Materials to Systems: Challenges and Solutions for Fast‐Charge/Discharge Na‐Ion Batteries
Advanced Energy Materials, EarlyView.This review systematically analyzes the key characteristics limiting the fast‐charge/discharge capability of Na‐ion batteries (SIBs) from a multi‐scale perspective encompassing electrode materials, the electrode‐electrolyte interface, and the system. Furthermore, it presents practical solution strategies for the fundamental issues arising at each scale,
Bonyoung Ku +5 more
wiley +1 more source
Quantitative proteomics identifies clusterin as a novel biomarker for atherosclerosis
Animal Models and Experimental Medicine, EarlyView.This schematic illustrates the proposed mechanism. In advanced atherosclerotic lesions, upregulated CLU on the cell surface activates low‐density lipoprotein (LDL) receptor‐related protein 1 (LRP1). This interaction triggers the phosphorylation and activation of AKT.
Dengfeng Ding +10 more
wiley +1 more source
Multifunctionality of silver closo-boranes
Nature Communications, 2017 Silver compounds have long been known to possess exceptional solid-state conductivity. Here the authors present silvercloso-boranes in which facile Ag+migration occurs, leading to exceptionally high ion conductivities and potential utility in silver ...
Mark Paskevicius +4 more
doaj +1 more source
In situ Synchrotron X-ray Thermodiffraction of Boranes
Crystals, 2016 Boranes of low molecular weight are crystalline materials that have been much investigated over the past decade in the field of chemical hydrogen storage.
Pascal G. Yot +2 more
doaj +1 more source
Polyhedral monocarbaborane chemistry. Carboxylic acid derivatives of the [closo-2-CB9H10](-) anion [PDF]
, 2004 Reaction of B10H14 with para-(OHC)C6H4(COOH) in aqueous KOH gives the [nido-6-CB9H11-6-(C6H4-para-COOH)](-) anion I which upon cluster closure with iodine in alkali solution gives the [closo-2-CB9H9-2-(C6H4-para-COOH)](-) anion 2; an analogous procedure ...
Franken, A., Kennedy, J.D., Kilner, C.A.
core +1 more source
Synthesis, structures and coordination chemistry of singly bridged phosphane-boranes with coordinately unsaturated platinum group metals [PDF]
, 2014 A range of singly bridged phosphane-boranes (PBs) have been investigated as potential ligands for basic transition metals. The PBs Ph2PC(Ph)=C(R)BR2 (R = Bu 1, Ph 2, Et 3), based on a rigid cis-ethylene bridges, have been prepared, improving upon limited
Allen +75 more
core +1 more source