Results 71 to 80 of about 20,491 (284)

Phosphido-borane-supported stannates

open access: yesDalton Transactions, 2023
While the reaction between three equivalents of the alkali metal phosphido-borane complexes [R2P(BH3)]M (M = Li, Na, K; R = Ph, iPr) with SnCl2gave the tris(phosphido-borane)stannates [M{R2P(BH3)}3Sn], similar reactions between [tBu2P(BH3)]M and SnCl2gave the known hydrido-stannate [M{tBu2P(BH3)}2Sn(H)].
Keith Izod   +3 more
openaire   +3 more sources

Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances

open access: yesEnergies, 2021
Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen ...
Carlos A. Castilla-Martinez   +3 more
doaj   +1 more source

Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors

open access: yesNature Communications, 2019
Polymers featuring p-block elements other than carbon are of interest for a range of applications, but access to highly-substituted examples remains challenging.
Nicola L. Oldroyd   +5 more
doaj   +1 more source

CO2 reduction with protons and electrons at a boron-based reaction center. [PDF]

open access: yes, 2019
Borohydrides are widely used reducing agents in chemical synthesis and have emerging energy applications as hydrogen storage materials and reagents for the reduction of CO2. Unfortunately, the high energy cost associated with the multistep preparation of
Essex, Laura A   +3 more
core  

A unified survey of Si-H and H-H bond activation catalysed by electron-deficient boranes [PDF]

open access: yes, 2015
The bond activation chemistry of B(C6F5)(3) and related electron-deficient boranes is currently experiencing a renaissance due to the fascinating development of frustrated Lewis pairs (FLPs).
Hermeke, Julia   +2 more
core   +1 more source

Sodium pentafluorophenylborate [PDF]

open access: yes, 2012
The crystal structure of the title compound, Na[(C6F5)BH3], is composed of discrete anions and cations. The sodium cations are surrounded by four anions with three short Na...B [2.848 (8), 2.842 (7) and 2.868 (8) Å] and two short Na...F contacts [2.348 ...
Bolte, Michael   +2 more
core   +1 more source

Aluminum Borate Nanowires from the Pyrolysis of Polyaminoborane Precursors [PDF]

open access: yes, 2016
Polyaminoboranes [N(R)H-BH2]n (1: R = H, 2: R = Me) were pyrolyzed on a range of substrates: silicon, metal foils (stainless steel, nickel, and rhodium), and sapphire wafers, as well as on Al2O3 and AlN powders.
Du, Van A   +3 more
core   +2 more sources

boranes

open access: yes, 2014
Citation: 'boranes' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.B00709 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms. Requests for commercial usage
openaire   +1 more source

Preservation therapy for vertically fractured teeth with periodontal tissue regeneration using FGF‐2

open access: yesClinical Advances in Periodontics, EarlyView.
Abstract Background Vertically fractured teeth often have a poor prognosis, and extraction is considered the most predictable treatment. Conventional management has consisted of preservation therapy involving extraction, bonding, root restoration, and replantation of fractured teeth.
Masaichiro Iwasaki   +4 more
wiley   +1 more source

Unsymmetrical Diboron Reagents: Application in Borylation Reactions of Unsaturated Bonds

open access: yesMolecules, 2019
In the past decades, borylation reactions have received extensive research interest and have developed into effective tools in the synthesis of versatile organoboron compounds. Boranes and symmetrical diboron compounds are commonly utilized as borylating
Siyi Ding, Liang Xu, Zongcheng Miao
doaj   +1 more source

Home - About - Disclaimer - Privacy