Results 31 to 40 of about 66,984 (246)

Trinuclear Magnesium Imidazolate Borohydride Complex

Inorganic Chemistry, 2022
A new type of hybrid compound, combining properties of MOFs and borohydrides, was synthesized solvothermally using Mg(BH4)2 and imidazole as precursors. Material in the form of acetonitrile solvate with formula [Mg3{(Im)BH2(Im)}6(ImH)6]·CH3CN crystallizes in the space group R3̅, having the unit cell parameters a = 15.1942(2) Å and c = 28.3157(3) Å as ...
Maja Reberc, Matjaž Mazaj, Jernej Stare, Marta Počkaj, Gregor Mali, Xiao Li, Yaroslav Filinchuk, Radovan Černý, Anton Meden   +8 more
openaire   +5 more sources

Surfactant-free synthesis of carbon-supported silver (Ag/C) nanobars as an efficient electrocatalyst for alcohol tolerance and oxidation of sodium borohydride in alkaline medium

SN Applied Sciences, 2021
We have synthesized carbon-supported silver (Ag/C) nanobars by a simple surfactant-free hydrothermal method using glucose as the reducing reagent as well as the source of carbon in Ag/C nanobars.
Santanu Dey, Pradipta Chakraborty, Dhiraj Kumar Rana, Subhamay Pramanik, Soumen Basu   +4 more
doaj   +1 more source

A combined "electrochemical-frustrated Lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes [PDF]

, 2014
Herein, we extend our “combined electrochemical–frustrated Lewis pair” approach to include Pt electrode surfaces for the first time. We found that the voltammetric response of an electrochemical–frustrated Lewis pair (FLP) system involving the B(C6F5)3 ...
Ashley, Ashley, Binding, Brown, Cauliez, Chapman, Chase, Chatgilialoglu, Compton, Croissant, de Leon, Duñach, Erker, Esteves, Fang, Farrell, Griller, Gritzner, Herrington, Holschumacher, Iwasita, Jutzi, Kolychev, Lawrence, Lawrence, Lawrence, LeSuer, Liu, Lu, Ma, Merino-Jiménez, Ménard, Mömming, Pedersen, Santos, Spies, Srivastava, Stephan, Stephan, Stephan, Stephan, Stephan, Sumerin, Tran, Travis, Welch, Welch, Whited, Zhang   +48 more
core   +2 more sources

Boron-Based (Nano-)Materials: Fundamentals and Applications

Crystals, 2016
The boron (Z = 5) element is unique. Boron-based (nano-)materials are equally unique. Accordingly, the present special issue is dedicated to crystalline boron-based (nano-)materials and gathers a series of nine review and research articles dealing with ...
Umit B. Demirci, Philippe Miele, Pascal G. Yot   +2 more
doaj   +1 more source

Dehydriding Process and Hydrogen–Deuterium Exchange of LiBH4–Mg2FeD6 Composites

Energies, 2015
The dehydriding process and hydrogen–deuterium exchange (H–D exchange) of xLiBH4 + (1 − x)Mg2FeD6 (x = 0.25, 0.75) composites has been studied in detail.
Guanqiao Li, Motoaki Matsuo, Katsutoshi Aoki, Tamio Ikeshoji, Shin-ichi Orimo   +4 more
doaj   +1 more source

Device for Controlled Production of Hydrogen

Hydrogen, 2023
In this work, the production of hydrogen from the sodium borohydride (NaBH4) reaction was studied using an experimental bench test in a passive device operating with or without minimal external energy input.
Alfonso Pozio
doaj   +1 more source

Development of polymeric hollow fiber membranes containing catalytic metal nanoparticules. [PDF]

, 2010
Metal nanoparticles (MNPs) have unique physico-chemical properties advantageous for catalytic applications which differ from bulk material. However, the main drawback of MNPs is their insufficient stability due to a high trend for aggregation.
Bruening, Merlin L., Lahitte, Jean-Francois, Macanás, Jorge, Muñoz, Maria, Ouyang, Lu, Remigy, Jean-Christophe   +5 more
core   +4 more sources

Hydrogen Sorption in Erbium Borohydride Composite Mixtures with LiBH4 and/or LiH

Inorganics, 2017
Rare earth (RE) metal borohydrides have recently been receiving attention as possible hydrogen storage materials and solid-state Li-ion conductors. In this paper, the decomposition and reabsorption of Er(BH4)3 in composite mixtures with LiBH4 and/or LiH ...
Michael Heere, Seyed Hosein Payandeh GharibDoust, Matteo Brighi, Christoph Frommen, Magnus H. Sørby, Radovan Černý, Torben R. Jensen, Bjørn C. Hauback   +7 more
doaj   +1 more source

Calcium Borohydride Ca(BH₄)₂: Fundamentals, Prediction and Probing for High-Capacity Energy Storage Applications, Organic Synthesis and Catalysis

Energies, 2023
Calcium borohydride (Ca(BH4)2) is a complex hydride that has been less investigated compared to its lighter counterpart, magnesium borohydride. While offering slightly lower hydrogen storage capacity (11.5 wt% theoretical maximum, 9.6 wt% under actual ...
Cezar Comanescu
doaj   +1 more source

Suppressing diborane production during the hydrogen release of metal borohydrides: The example of alloyed Al(BH$_4$)$_3$

, 2016
Aluminum borohydride (Al(BH$_4$)$_3$) is an example of a promising hydrogen storage material with exceptional hydrogen densities by weight and volume and a low hydrogen desorption temperature.
Harrison, D., Thonhauser, T.
core   +1 more source