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Boronated Cyanometallates

open access: yesInorganic Chemistry, 2022
Fourteen boronated cyanometallates ([M(CN-BR3)6]3/4/5– (M = Cr, Mn, Fe, Ru, Os, R = BPh3, B(2,4,6,-F3C6H2)3, B(C6F5)3) have been characterized by X-ray crystallography and spectroscopy [UV-vis-NIR, NMR, IR, spectroelectrochemistry, and magnetic circular dichroism (MCD)]; CASSCF+NEVPT2 methods were employed in calculations of electronic structures. For (
Brendon J. McNicholas   +12 more
openaire   +3 more sources

Hydrophosphination of boron–boron multiple bonds

open access: yesChemical Science, 2020
Compounds containing boron–boron double and triple bonds are shown to undergo uncatalysed hydrophosphination reactions with diphenylphosphine.
Tom E. Stennett   +4 more
openaire   +4 more sources

Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond [PDF]

open access: yesAngewandte Chemie International Edition, 2020
AbstractAn N‐heterocyclic‐carbene‐stabilized diboryne undergoes rapid, high‐yielding and catalyst‐free hydroamination reactions with primary amines, yielding 1‐amino‐2‐hydrodiborenes, which can be considered boron analogues of enamines. The electronics of the organic substituent at nitrogen influence the structure and further reactivity of the diborene
Tobias Brückner   +4 more
openaire   +4 more sources

Boron

open access: yesChemInform, 2003
AbstractFor Abstract see ChemInform Abstract in Full Text.
openaire   +6 more sources

The symmetry of the boron buckyball and a related boron nanotube [PDF]

open access: yesChemical Physics Letters, 2010
4 pages, 3 ...
N. Gonzalez Szwacki, C. J. Tymczak
openaire   +3 more sources

Boron [PDF]

open access: yesAdvances in Nutrition, 2020
Forrest H Nielsen, Curtiss D Eckhert
openaire   +2 more sources

Bonding with boron [PDF]

open access: yesNature Chemistry, 2009
Long ago, a global search for borane superfuels led fortuitously to the discovery of carboranes. Ken Wade recalls his own undistinguished part in the space race, and notes how carboranes revitalized boron hydride chemistry and modified our ideas of chemical bonding.
openaire   +2 more sources

Plasma boron and the effects of boron supplementation in males.

open access: yesEnvironmental Health Perspectives, 1994
Recently, a proliferation of athletic supplements has been marketed touting boron as an ergogenic aid capable of increasing testosterone. The effect of boron supplementation was investigated in male bodybuilders. Ten male bodybuilders (aged 20 to 26) were given a 2.5-mg boron supplement, while nine male bodybuilders (aged 21 to 27) were given a placebo
Arny A. Ferrando, Nancy R. Green
openaire   +3 more sources

Boron and boron carbide by vapor deposition

open access: yesElectrodeposition and Surface Treatment, 1974
Abstract Boron trichloride can be reduced by hydrogen at 1,300°C with a recovery of approximately 85% as elemental boron. The optimum H2 to BCl3 molar ratio was 30 under the test conditions used. No reaction between tungsten substrates and the boron deposits could be detected.
J.G. Donaldson   +2 more
openaire   +3 more sources

Preparation of boron [PDF]

open access: yesThe London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science
n ...
openaire   +3 more sources

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