Results 1 to 10 of about 342,443 (227)
Fourteen boronated cyanometallates ([M(CN-BR3)6]3/4/5– (M = Cr, Mn, Fe, Ru, Os, R = BPh3, B(2,4,6,-F3C6H2)3, B(C6F5)3) have been characterized by X-ray crystallography and spectroscopy [UV-vis-NIR, NMR, IR, spectroelectrochemistry, and magnetic circular dichroism (MCD)]; CASSCF+NEVPT2 methods were employed in calculations of electronic structures. For (
Brendon J. McNicholas+12 more
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Hydrophosphination of boron–boron multiple bonds
Compounds containing boron–boron double and triple bonds are shown to undergo uncatalysed hydrophosphination reactions with diphenylphosphine.
Tom E. Stennett+4 more
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Synthesis of Boron Analogues of Enamines via Hydroamination of a Boron−Boron Triple Bond [PDF]
AbstractAn N‐heterocyclic‐carbene‐stabilized diboryne undergoes rapid, high‐yielding and catalyst‐free hydroamination reactions with primary amines, yielding 1‐amino‐2‐hydrodiborenes, which can be considered boron analogues of enamines. The electronics of the organic substituent at nitrogen influence the structure and further reactivity of the diborene
Tobias Brückner+4 more
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The symmetry of the boron buckyball and a related boron nanotube [PDF]
4 pages, 3 ...
N. Gonzalez Szwacki, C. J. Tymczak
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Long ago, a global search for borane superfuels led fortuitously to the discovery of carboranes. Ken Wade recalls his own undistinguished part in the space race, and notes how carboranes revitalized boron hydride chemistry and modified our ideas of chemical bonding.
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Plasma boron and the effects of boron supplementation in males.
Recently, a proliferation of athletic supplements has been marketed touting boron as an ergogenic aid capable of increasing testosterone. The effect of boron supplementation was investigated in male bodybuilders. Ten male bodybuilders (aged 20 to 26) were given a 2.5-mg boron supplement, while nine male bodybuilders (aged 21 to 27) were given a placebo
Arny A. Ferrando, Nancy R. Green
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Boron and boron carbide by vapor deposition
Abstract Boron trichloride can be reduced by hydrogen at 1,300°C with a recovery of approximately 85% as elemental boron. The optimum H2 to BCl3 molar ratio was 30 under the test conditions used. No reaction between tungsten substrates and the boron deposits could be detected.
J.G. Donaldson+2 more
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