Results 121 to 130 of about 6,117,045 (351)

4D‐Printable Poly(Thio)urethane Photoresins With Reactive Oxygen Species Responsiveness and Anti‐Inflammatory Functionality

open access: yesAdvanced Functional Materials, EarlyView.
This work introduces UV‐curable poly(thio)urethane (PSU) thermosets as 4D printable scaffolds responsive to oxidative stress. PSU networks with 100 wt.% polypropylene glycol (PPG) effectively suppress inflammatory markers in microglial cells to basal values.
Xabier Lopez de Pariza   +10 more
wiley   +1 more source

Examining the PM6 semiempirical method for pKa prediction across a wide range of oxyacids [PDF]

open access: yes, 2009
The pK~a~ estimation ability of the semiempirical PM6 method was evaluated across a broad range of oxyacids and compared to results obtained using the SPARC software program.
Kaya Forest   +2 more
core   +1 more source

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones [PDF]

open access: yes, 2015
Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all ...
Beattie, N. A.   +4 more
core   +1 more source

Light Activated Induction of Cuproptosis in Resistant Cancer Cells Using Polymeric BODIPY Nanoparticles for Photoactivated Chemotherapy

open access: yesAdvanced Functional Materials, EarlyView.
This article presents a photo‐responsive nanoparticle platform that precisely triggers copper‐dependent cuproptotic cell death in (drug‐resistant) cancer cells. The system remains stable and inactive in the dark but releases cytotoxic species upon red‐light irradiation, achieving potent activity in drug‐resistant breast cancer cells.
Ricarda Zimmermann   +2 more
wiley   +1 more source

Engineering Strategies for Stable and Long‐Life Alkaline Zinc‐Based Flow Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Alkaline zinc‐based flow batteries face persistent challenges from unstable zinc deposition, including dendrite growth, passivation, corrosion, and hydrogen evolution, which severely limit cycling stability. Current research addresses these issues through coordinated electrode structuring, electrolyte regulation, and membrane design to control zinc ...
Yuran Bai   +6 more
wiley   +1 more source

Investigation of the Interaction between Ferroceneboronic Acid and Sugars and Its Application in Probing of Enzyme Activity

open access: yesInternational Journal of Electrochemical Science, 2013
Sugars play important roles in many biological processes, such as nutrition, metabolism, cell structure formation, and immunological protection. Phenylboronic acid (PBA) derivatives have been widely used as recognition molecules for sugars based on the ...
Xiaojin Wang   +4 more
doaj   +1 more source

Stereospecific and chemoselective copper-catalyzed deaminative silylation of benzylic ammonium triflates [PDF]

open access: yes, 2019
A method for the synthesis of benzylsilanes starting from the corresponding ammonium triflates is reported. Silyl boronic esters are employed as silicon pronucleophiles, and the reaction is catalyzed by copper(I) salts.
Gross, Benjamin M.   +2 more
core   +1 more source

Single‐ and Dual‐Atom Configurations in Atomically Dispersed Catalysts for Lithium–Sulfur Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Single‐atom and dual‐atom‐based atomically dispersed catalysts (ADCs) effectively address the shuttle effect and sluggish redox kinetics in Li–S batteries. With nearly 100% atomic utilization and tunable coordination environments, ADCs enhance LiPSs adsorption, lower conversion barriers, and accelerate sulfur redox reactions.
Haoyang Xu   +4 more
wiley   +1 more source

A new, substituted palladacycle for ppm level Pd-catalyzed Suzuki-Miyaura cross couplings in water. [PDF]

open access: yes, 2019
A newly engineered palladacycle that contains substituents on the biphenyl rings along with the ligand HandaPhos is especially well-matched to an aqueous micellar medium, enabling valued Suzuki-Miyaura couplings to be run not only in water under mild ...
Gallou, Fabrice   +5 more
core  

Atropselective syntheses of (-) and (+) rugulotrosin A utilizing point-to-axial chirality transfer [PDF]

open access: yes, 2015
Chiral, dimeric natural products containing complex structures and interesting biological properties have inspired chemists and biologists for decades.
A Zask   +53 more
core   +2 more sources

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