Direct Boronic Acid Promoted Amidation of Carboxylic Acids with Poorly Nucleophilic Amines
Direct amidation of carboxylic acids with poorly nucleophilic amines such as anilines is a notorious challenge in organic chemistry. Previously reported methodologies for direct amidation tend to report none or just a few examples with simple anilines ...
Zhou, Jingning +2 more
core +1 more source
Interdependent Dynamic Nitroaldol and Boronic Ester Reactions for Complex Dynamers of Different Topologies [PDF]
Complex dynamic systems displaying interdependency between nitroaldol and boronic ester reactions have been demonstrated. Nitroalkane-1,3-diols, generated by the nitroaldol reaction, were susceptible to ester formation with different boronic acids in ...
Mubarak, Ayinla +4 more
core +2 more sources
Anomeric sugar boronic acid analogues as potential agents for boron neutron capture therapy
After the development of accelerators as neutron source, the access to new suitable agents for boron neutron capture therapy (BNCT) became a major need. Among many others, sugar boronic acids have recently attracted attention as boron carriers. Herein we
Daniela Imperio +4 more
doaj +1 more source
β-Citronellol as a sustainable additive for mechanochemical Suzuki–Miyaura cross-coupling reactions [PDF]
Here, it is found that β-citronellol enables the mechanochemical cross-coupling reactions of various aryl halides and aryl boronic acids in moderate to excellent yields under ambient conditions using low-cost or no phosphine ligand and without the ...
Tanzida Zubair +3 more
doaj +1 more source
ChemInform Abstract: Double Couplings of Dibromothiophenes Using Boronic Acids and Boronates. [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Samantha, Varello, Scott T, Handy
openaire +2 more sources
Oxidative Coupling of Aryl Boronic Acids with Aryl- and Alkylamines via Cooperative Photoredox and Copper Catalysis [PDF]
Copper(II)-catalyzed oxidative cross-couplings of aryl boronic acids with aryl- and alkylamines have been accomplished across a range of substrates in the presence of a ruthenium(II)-photoredox cocatalyst under mild aerobic conditions.
Jennifer, Marshall +2 more
core +2 more sources
Boronic Acid-Based Electrochemical Sensors for Detection of Biomolecules
Boronic acids can form reversible covalent bonds with 1, 2- or 1, 3-diols to generate five or six-membered cyclic complexes. Thus, boronic acid functionalized compounds and materials have attracted much attention in both chemistry and biology as the ...
Lin Liu, Ning Xia, Yun Xing, Dehua Deng
doaj +1 more source
Targeted delivery of boronic acids through bioconjugation
In oncology, a predicament becomes apparent when considering the shared nature of a tumor and healthy tissue. Traditional chemotherapy employs potent cytotoxic small molecules with reasonable selectivity for rapidly-dividing cells.
Lopes, Ricardo M. R. M.
core
New strategies in Bioconjugation : chemical modification of nucleic acids and peptides [PDF]
One of the open challenges in chemical biology is to identify reactions that proceed with large rate constants in water at neutral pH values. Once assembled, these conjugates may be used for a broad variety of applications (e.g., therapeutics, imaging ...
Schmidt, Pascal Jarno
core +1 more source
Multidisciplinary applications of four-coordinate boron(III) complexes make them very attractive and challenging research field in chemistry, biology and material sciences.
Venkata S. Sadu +3 more
doaj +1 more source

