Results 21 to 30 of about 78,896 (178)

Synthesis and characterization of a new photoinduced switchable β-cyclodextrin dimer

open access: yesBeilstein Journal of Organic Chemistry, 2014
This paper reports an efficient preparation of bridged bis-β-CD AZO-CDim 1 bearing azobenzene as a linker and exhibiting high solubility in water. The photoisomerization properties were studied by UV–vis and HPLC and supported by ab initio calculations ...
Florian Hamon   +10 more
doaj   +1 more source

Crystal structures of an azobenzene-bridged aza-18-crown-6 cryptand and a sodium complex thereof

open access: yesActa Crystallographica Section E: Crystallographic Communications
We report the single-crystal X-ray diffraction structures of the azobenzene-bridged aza-18-crown-6 cryptand 7,16-[3,3′-(diazene-1,2-diyl)bis(1,3-phenylenecarbonyl)]-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, C26H32N4O6, 1, and its sodium complex poly[[
Christoph Schwab, Elisabeth Kreidt
doaj   +1 more source

Carbonyl-bridged trifluoromethyl pyridine derivatives for pest control and mechanistic investigations

open access: yesAdvanced Agrochem
Trifluoromethyl pyridine (TFMP) motif is commonly discovered in structures of active pharmaceuticals. Flonicamid, characterized by the TFMP moiety, is well known as a prodrug in the knockdown of pests.
Zhubo Sheng   +7 more
doaj   +1 more source

Self-Directed Assembly of Photoactive Hybrid Silicates Derived from an Azobenzene-Bridged Silsesquioxane

open access: yes, 2016
Hybrid silicate materials derived from organo-bridged silsesquioxane precursors, RO3−Si−R‘−Si−OR3, where R and R‘ are organic ligands, represent a remarkably diverse class of nanocomposites capable of forming both Si−O−Si and Si−C−Si bonds with molecular
Ying-Bing Jiang (1721821)   +5 more
core   +1 more source

Hydrogel platforms for 3D cardiac tissue engineering and fibrotic disease modelling

open access: yesFEBS Open Bio, EarlyView.
Hydrogel‐based cardiac tissue models are advancing our understanding of heart health and disease. By incorporating electrical conductivity, aligned structures, and tunable mechanical properties, these platforms better replicate the complex environment of native heart tissue.
Harrison Porritt   +2 more
wiley   +1 more source

Molecular Preorganization Unlocks Reversible Solid‐State Photoconversion in Dianthrylnaphthalene‐Based Molecular Solar Thermal Systems

open access: yesAngewandte Chemie, EarlyView.
Three dianthrylnaphthalenes were synthesized and investigated for molecular solar thermal (MOST) energy storage. Naphthyl‐based bridging units preorganize the two anthracene moieties face‐to‐face, leading to improved photoisomerization quantum yield (QY) and unlocked bidirectional photoswitching in the solid state compared to previously reported ortho ...
Nicolò Baggi   +10 more
wiley   +2 more sources

Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices

open access: yesAdvanced Functional Materials, EarlyView.
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies   +2 more
wiley   +1 more source

Optical Control of the Glucocorticoid Receptor Activity With a Photoswitchable Agonist

open access: yesAngewandte Chemie, EarlyView.
A photoswitchable glucocorticoid receptor agonist enables optical control of receptor activity, achieving picomolar potency and partial agonism that preferentially maintains anti‐inflammatory signaling over canonical transcriptional activation. ABSTRACT Glucocorticoids (GCs) are widely prescribed anti‐inflammatory agents whose clinical utility is ...
Zoe Sessions   +8 more
wiley   +2 more sources

“Smelltronics”—From Gas to Smell Sensing

open access: yesAdvanced Materials, EarlyView.
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono   +7 more
wiley   +1 more source

Light-driven nanofiber and nanoring morphological transformations in organogels based on an azobenzene-bridged biscalix[4]arene

open access: yes, 2017
The morphologies of an azobenzene-bridged biscalix[4]arene organogel (1) in different organic solvents can be photo-reversibly switched between nanofibers and nanorings as well as between closed and open-form vesicles.
Pei-Mei Su   +4 more
core   +1 more source

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