Results 11 to 20 of about 3,559 (85)

Light‐Enabled [2σ + 2π] Cycloadditions of Bicyclo[1.1.0]butanes and Alkenes by Ti‐Salen Photocatalysis

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
This study reports an unprecedented Ti(Salen)‐catalyzed [2σ+2π] photocycloaddition of bicyclo[1.1.0]butanes and alkenes, featuring broad substrate scope, excellent functional group tolerance, scalability, and potential pharmaceutical applications. Notably, this work represents the first application of a Ti(Salen) complex as an efficient photoredox ...
Jinping Xing   +5 more
wiley   +1 more source

Unlocking Biomolecule Modification with Light‐Promoted Photocatalyst‐Free Approaches: Current Tools, Challenges, and Perspectives

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
This Perspective focuses on photocatalyst‐free, photoinduced modifications of biomolecules, emphasizing transformations mediated by electron donor–acceptor complexes. Mechanistic aspects, current limitations, and future opportunities are discussed, providing insight into the field of bioconjugation.
Milene Hornink   +3 more
wiley   +1 more source

Exploring Isophorone‐Based Dienones: Comprehensive Insights Into Their Synthesis, Reactivity, and Diverse Applications

open access: yesJournal of Chemistry, Volume 2026, Issue 1, 2026.
Isophorone is an important motif in synthetic organic chemistry, as it is highly reactive and can get involved in a diverse array of functional group transformations to access various synthetic intermediates and molecular targets. In this context, an important group of compounds is the conjugated or nonconjugated isophorone‐cored dienones, which are ...
M. Saeed Abaee   +2 more
wiley   +1 more source

Visible‐Light Mediated Activation of 1,3‐Dienes and Allenes via Energy Transfers

open access: yesChemistry – A European Journal, Volume 31, Issue 67, December 1, 2025.
Nature has inspired chemists to develop photocatalytic processes that harness visible light, offering alternative reaction pathways beyond traditional thermal methods. Energy Transfer (EnT) is a particularly promising strategy, enabling transformations such as isomerization, deracemization, cycloadditions, and cascade reactions.
Scarica Gabriele   +6 more
wiley   +1 more source

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

open access: yesSmart Molecules, Volume 3, Issue 4, December 2025.
Block copolymers are fundamental for the development of smart molecules. Aliphatic polyesters and polycarbonates have received attention as heteroatom‐containing polymers that are biodegradable and biocompatible. Block polymers from polyesters and polycarbonates have the ability to form smart molecules. This review presents the heterocycle monomer ring‐
Hongyu Zhao   +3 more
wiley   +1 more source

Recent Synthetic Advances in C–H/N–H Functionalization of 1H‐Pyrazoles: Diverse Strategies Across Variously Substituted Scaffolds

open access: yesThe Chemical Record, Volume 25, Issue 12, December 2025.
Systematic overview of pyrazole functionalization reactions from C‐5 to N−H. It covers different strategies, from traditional cross‐coupling of prefunctionalized pyrazoles to more efficient direct functionalizations. This review briefly and systematically overviews C–H and N–H functionalization reactions of pyrazoles, aimed at creating new CC and C ...
Karolina Dzedulionytė Müldür   +3 more
wiley   +1 more source

Hetero[3.1.1]propellanes. [PDF]

open access: yesNat Chem
Revie RI   +5 more
europepmc   +1 more source

Synthesis of aryl-fused bicyclo[3.1.1]heptanes and validation as naphthyl bioisosteres. [PDF]

open access: yesNat Chem
Kerckhoffs A   +12 more
europepmc   +1 more source

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