Results 131 to 140 of about 65,001 (335)

On bromine [PDF]

open access: yesThe Philosophical Magazine
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openaire   +2 more sources

Coupled Photocatalytic Hydrogen Production With Selective Biomass Valorization via Active Sites Construction and Electron Transport Channels Engineering

open access: yesCarbon Energy, EarlyView.
A ternary CdS/1T‐WS2/CNTs heterojunction is in‐situ constructed via hydrothermal method, which is used for photocatalytic biomass reforming (biomass‐derived alcohols, lignin). It exhibits outstanding performance: H2 production rate of 26.17 mmol/g/h for benzyl alcohol (BA), benzaldehyde (BD) generation rate of 8.29 mmol/g/h, 90.06% BD selectivity, 100%
Ermiao Liang   +11 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

High-temperature bromination XIII: Bromination of dimethyl 7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate

open access: yes, 2001
The electrophilic addition of bromine to dimethyl 7-oxabicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate 10 at 0 and -60 degreesC led in high yield to the formation of dibromide 11.
Arici, C   +5 more
core   +1 more source

A Gram Scale Synthesis of 3,4-Dihalogen Substituted 1,8-Naphthalimides

open access: yesMolbank
A general protocol for the synthesis of 3,4-dihalogen substituted 1,8-naphthalimides is proposed, starting from available and cheap 1,8-naphthalic anhydride.
Denitsa Anastasova   +6 more
doaj   +1 more source

The One‐Step Synthesis of Biologically Active Isochromans from Lignin‐Derived Aromatic Monomers in Tunable Deep Eutectic Solvents

open access: yesChemistry – A European Journal, EarlyView.
A straightforward one‐step protocol enables the synthesis of bio‐based and biologically active isochromans through the Oxa‐Pictet cyclization involving diverse aldehydes, including vanillin in combination with lignin‐derivable homovanillyl alcohol, a prominent aromatic platform chemical obtainable via diol‐assisted fractionation of lignocellulose ...
Anjali Kottayi   +6 more
wiley   +1 more source

Determination of Rubber Hydrocarbon by a Modified Bromination Method

open access: yes, 1952
Published investigations show that, in the bromination of rubber, addition is accompanied by some substitution. The substitution portion of the bromination reaction is difficult to control and has contributed to low results and occasional poor precision.
William J. Gowans, Frederick E. Clark
core   +1 more source

Sunlight‐Driven Green Synthesis of Platinum Nanoparticles From Double‐Vacancy Halide Perovskite Precursors for Methanol Reforming

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The development of synthetic procedures for preparing metal nanoparticles with controlled size using sunlight opens new avenues toward more sustainable methods with lower energy consumption. Herein, we propose the use of double‐vacancy halide perovskites as precursors for engineering highly crystalline and small platinum nanoparticles (< 3 nm)
Kevin Mego   +4 more
wiley   +1 more source

High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao   +8 more
wiley   +1 more source

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