Results 151 to 160 of about 65,001 (335)
Regiospecific bromination of condensed tetralones via aryloxydifluoroboron chelates
Bromination (Br2, CCl4) of the anthracenone derivative (1b) under thermal or photochemical conditions gives the expected bromo-compound (1d) whereas photochemical bromination of the aryloxydifluoroboron complexes (2a,b) gives products (2c,d) of benzylic ...
Morley, John O. +3 more
core
Organo‐functionalized molecular molybdenum sulfides were synthesized using bidentate N‐donor ligands and investigated as light‐driven homogeneous hydrogen evolution reaction (HER) catalysts. Trends observed in the HER activity of these catalysts were elucidated by combining photophysical, electrochemical and computational studies.
Moritz Jahn +9 more
wiley +1 more source
FLP Mediated Conversion of Difluorobenzylalkynes to Fluoroallenyl Oniums via an SN1’ Pathway
Frustrated Lewis pair (FLP) selective C‒F activation of difluorobenzylalkynes allows the formation of fluoroallenic oniums via an SN1’ substitution pathway. The fluoroallenic onium salts are synthetic precursors that allow subsequent functionalization at allenic and onium positions.
Max Coles +6 more
wiley +1 more source
Enzymatic Bromination of Native Peptides for Late-Stage Structural Diversification via Suzuki-Miyaura Coupling. [PDF]
Bridge HN, Radziej CL, Weeks AM.
europepmc +1 more source
A series of hydrosoluble BODIPY pH probes allows building biomimetic pH sensors based on micrometric oil‐in‐water droplets. The ratiometric fluorescence output offers quantitative information on the evolution of pH during phagosome maturation. ABSTRACT We present a modular biomimetic fluorescent sensing platform designed to precisely interrogate the ...
Sophie Michelis +5 more
wiley +1 more source
Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal +3 more
wiley +1 more source
The electrophilic addition of Br to 'endo-benzocyclobutanorbornene' 5 at -50degrees led in high yield to the formation of the rearranged dibromides 6 and 7.
BALCI, M, Dastan, Arif, UZUNDUMLU, E
core
Site-selective bromination of anthracene-maleimide Diels-Alder crystals for tunable afterglow and white light emission. [PDF]
Yang G +5 more
europepmc +1 more source

