Results 121 to 130 of about 92,840 (303)

Developments of catalysts for the direct conversion of aqueous ethanol to butadiene

Green Carbon
1,3-Butadiene is an important chemical raw material, especially with its large market demand as the main monomer for rubber tires. It is mainly produced by the thermal cracking of naphtha as a by-product of olefin production. The production process faces
Na Liu, Mingkai Wang, Yijun Zhou, Lishu Shao, Lin Zhang, Peng Zhan, Zhiping Wu   +6 more
doaj   +1 more source

Cluster Analysis of Circular Economy and Industrial Symbiosis Practices and Their Impact on Sustainability Performance in the Plastics Industry

Business Strategy and the Environment, EarlyView.
ABSTRACT This study examines how plastics manufacturing firms can be classified according to their level of implementation of circular economy (CE) and industrial symbiosis (IS) practices and how such adoption influences sustainability performance. Using data from plastics manufacturing firms, we integrate cluster analysis with partial least squares ...
Laura Cristina Ramírez‐Rodríguez, Rafael Mora‐Contreras, Carmen Jaca, Marta Ormazabal   +3 more
wiley   +1 more source

Substituent‐Controlled Ring Opening of 1‐Substituted Benzocyclobutenes: Electronic Structure and Diradical Character of Ortho‐Quinodimethane Intermediates

Chemistry – A European Journal, EarlyView.
Experimental and computational studies elucidate how the electronic nature of substituents controls the ring‐opening temperature and diradical character of 1‐substituted benzocyclobutenes, enabling the rational design of o‐quinodimethane‐based synthetic transformations.
Magali Dallegre, Imen Abid, Roselyne Rosas, Maxime Dousset, Gaëlle Chouraqui, Laurent Commeiras, Didier Siri, Didier Gigmes, Anthony Kermagoret   +8 more
wiley   +1 more source

Strain Release of 1‐Azabicyclo[1.1.0]butanes as a Gateway to Highly Functionalized Azetidines: New Strategies and Structural Motifs

Chemistry – A European Journal, EarlyView.
Over the past decade, the interest in azetidines has continuously risen, by virtue of their highly appealing pharmaceutical properties. Monocyclic, spirocyclic, and bridged azetidines can be accessed by leveraging 1‐azabicyclo[1.1.0]butanes as precursors.
Yuri Gelato, Philipp Natho, Marco Colella, Renzo Luisi   +3 more
wiley   +1 more source

Polarity on Demand: Nucleophilic, Electrophilic, and Ambiphilic Reactivity at a 9,10‐Dihydro‐9,10‐Disilaanthracene Platform

Chemistry – A European Journal, EarlyView.
A 9,10‐dihydro‐9,10‐disilaanthracene platform was efficiently synthesized and features intrinsically electrophilic Si sites. Upon stepwise reductive Si─H bond cleavage, these Si sites are converted into nucleophilic centers. This controlled polarity switching also enables ambiphilic reactivity within a homo‐heteroelement framework.
Moritz Schmidt, Alexander Virovets, Eugenia Peresypkina, Hans‐Wolfram Lerner, Matthias Wagner   +4 more
wiley   +1 more source

Geometrical influences on non-radiative processes in organic molecules Progress report [PDF]

Ground and excitated states of planar and distorted configurations of organic ...
Evleth, E. M.
core   +1 more source

Dinuclear Group 4 Metallocene Catalysts of the Type [(Cp2M)2(μ‐Me)(μ‐C2R)]: Structure‐Activity Relationships in Ethylene Polymerization

Chemistry – A European Journal, EarlyView.
Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi, Mirko Rippke, Anke Spannenberg, Michal Horáček, Jiří Pinkas, Vojtěch Varga, Martin Lamač, Fabian Reiß, Torsten Beweries   +8 more
wiley   +1 more source

Modelling of continuous low‐temperature emulsion co‐polymerization in 3D‐printed reactor

The Canadian Journal of Chemical Engineering, EarlyView.
A kinetic model for the emulsion copolymerization of butyl acrylate/styrene at low temperatures is proposed and validated against experiments with a redox initiator system. The model was successfully transferred to a 3D‐printed tubular reactor and conversions of more than 80% and small particles sizes below 40 nm were observed.
Ferel Issa, Andreas Reinbeck, Kristina M. Zentel   +2 more
wiley   +1 more source

MIL-53(Al)-derived bimetallic Pd–Co catalysts for the selective hydrogenation of 1,3-butadiene at low temperature

Scientific Reports
Selective hydrogenation of 1,3-butadiene is a crucial industrial process for the removing of 1,3-butadiene, a byproduct of butene production. Developing catalysts with high catalytic performance for the hydrogenation of 1,3-butadiene at low temperatures ...
Lili Liu, Miaoliang Zang, Lei Li, Yunkai Zhang, Leyuan Wang, Xiaojing Zhou, Chunling Xin, Xishi Tai   +7 more
doaj   +1 more source

Construction and application of green production assessment index system for styrene-butadiene rubber industry

Hecheng xiangjiao gongye
Aiming at the entire production process from raw material selection to product delivery, a green production assessment framework model for styrene-butadiene rubber industry was proposed, and an assessment index system for green production of styrene ...
LI Xiao-yin, SONG Jie-rui, ZHAO Hui-hui, CHEN Gen-ping
doaj   +1 more source