Results 1 to 10 of about 7,841,690 (187)

C–H Activation: Toward Sustainability and Applications

ACS Central Science, 2021
Since the definition of the “12 Principles of Green Chemistry” more than 20 years ago, chemists have become increasingly mindful of the need to conserve natural resources and protect the environment through the judicious choice of synthetic routes and ...
Toryn Dalton, Teresa Faber, Frank Glorius   +2 more
doaj   +2 more sources

Visible light-driven C−H activation and C–C coupling of methanol into ethylene glycol

Nature Communications, 2018
Direct transformation of methanol into two- or multi-carbon compounds is extremely attractive but remains a challenge. Here, the authors report an efficient photocatalytic route to the transformation of methanol into ethylene glycol and hydrogen over a ...
Shunji Xie, Zebin Shen, Jiao Deng, Pu Guo, Qinghong Zhang, Haikun Zhang, Chao Ma, Zheng Jiang, Jun Cheng, Dehui Deng, Ye Wang   +10 more
doaj   +2 more sources

Asymmetric S=N-embedded polyaromatic construction via enantioselective Pd-catalyzed C–H activation [PDF]

Nature Communications
Heteroatom-doped polyaromatic hydrocarbons show great potential for advancing photoelectric materials. SVI=N doping, characterized by soft-hard atom binding, donor-acceptor transmission, and chiroptical tuning, provides a powerful approach for further ...
Daming Zeng, Xinyu Zhang, Ming Wang, Xuefeng Jiang   +3 more
doaj   +2 more sources

Light-driven C–H activation mediated by 2D transition metal dichalcogenides [PDF]

Nature Communications
C–H bond activation enables the facile synthesis of new chemicals. While C–H activation in short-chain alkanes has been widely investigated, it remains largely unexplored for long-chain organic molecules.
Jingang Li, Di Zhang, Zhongyuan Guo, Zhihan Chen, Xi Jiang, Jonathan M. Larson, Haoyue Zhu, Tianyi Zhang, Yuqian Gu, Brian W. Blankenship, Min Chen, Zilong Wu, Suichu Huang, Robert Kostecki, Andrew M. Minor, Costas P. Grigoropoulos, Deji Akinwande, Mauricio Terrones, Joan M. Redwing, Hao Li, Yuebing Zheng   +20 more
doaj   +2 more sources

Nickel(II)/BINOL-catalyzed enantioselective C–H activation via desymmetrization and kinetic resolution [PDF]

Nature Communications
The field of nickel catalysis has witnessed remarkable growth in recent years. However, the use of nickel catalysts in enantioselective C–H activation remains a daunting challenge because of their variable oxidation states, intricate coordination ...
Qi-Jun Yao, Fan-Rui Huang, Jia-Hao Chen, Bing-Feng Shi   +3 more
doaj   +2 more sources

Photocatalytic C−H activation and C−C coupling of monohydric alcohols

Catalysis Communications, 2021
Monohydric alcohols, such as methanol, ethanol, are useful chemical building blocks that can be facilely produced from various carbon resources. The direct conversion of alcohols into high-value-added chemicals, in particular diols, is attractive but ...
Limei Wang, Zongyi Huang, Shunji Xie, Qinghong Zhang, Haiyan Wang, Ye Wang   +5 more
doaj   +1 more source

Au-Catalyzed Cross-Coupling of Arenes via Double C–H Activation [PDF]

Journal of the American Chemical Society, 2015
The first methodology for Au(I/III)-catalyzed oxidative cross-coupling of arenes via double C-H activation has been developed. The reaction is fully selective for the cross-coupling between electron-rich hetero-/carbocyclic arenes and electron-poor arenes bearing relatively acidic C-H bonds.
Cambeiro, XC, Ahlsten, N, Larrosa, I
openaire   +6 more sources

Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid

Nature Communications, 2022
The selective oxidation of glycerol to glyceric acid, an important value-added reaction from polyols, is a typical cascade catalytic process. It is still of great challenge to simultaneously achieve high glycerol activity and glyceric acid selectivity ...
Z. An, Zilong Zhang, Zeyu Huang, Hongbo Han, Binbin Song, Jian Zhang, Q. Ping, Yanru Zhu, Hongyan Song, Bin Wang, Lirong Zheng, Jing He   +11 more
semanticscholar   +1 more source

Strategies to transform remote C(sp3)-H bonds of amino acid derivatives

Tetrahedron Chem, 2022
Amino acids and peptides play an important role in nature as well as in the pharmaceutical industry. Therefore, transformation of amino acids and peptides into their unnatural derivatives via step and atom economical ways is highly demanding. Although, a
Supreeta Sen, Jayabrata Das, Debabrata Maiti   +2 more
doaj   +1 more source

Steam-created grain boundaries for methane C–H activation in palladium catalysts

Science, 2021
Description Going with the grain Changes in surface structure can make metal nanoparticles supported on oxides more active for certain catalytic reactions. Huang et al.
Weixin Huang, A. Johnston-Peck, Trenton J. Wolter, Wei-Chang D. Yang, Lang Xu, Jinwon Oh, Benjamin A. Reeves, Chengshuang Zhou, M. Holtz, A. Herzing, A. Lindenberg, M. Mavrikakis, M. Cargnello   +12 more
semanticscholar   +1 more source