Results 1 to 10 of about 3,837,372 (238)
Asymmetric S=N-embedded polyaromatic construction via enantioselective Pd-catalyzed C–H activation [PDF]
Nature CommunicationsHeteroatom-doped polyaromatic hydrocarbons show great potential for advancing photoelectric materials. SVI=N doping, characterized by soft-hard atom binding, donor-acceptor transmission, and chiroptical tuning, provides a powerful approach for further ...
Daming Zeng +3 more
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Light-driven C–H activation mediated by 2D transition metal dichalcogenides [PDF]
Nature CommunicationsC–H bond activation enables the facile synthesis of new chemicals. While C–H activation in short-chain alkanes has been widely investigated, it remains largely unexplored for long-chain organic molecules.
Jingang Li +20 more
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Nickel(II)/BINOL-catalyzed enantioselective C–H activation via desymmetrization and kinetic resolution [PDF]
Nature CommunicationsThe field of nickel catalysis has witnessed remarkable growth in recent years. However, the use of nickel catalysts in enantioselective C–H activation remains a daunting challenge because of their variable oxidation states, intricate coordination ...
Qi-Jun Yao +3 more
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Photocatalytic C−H activation and C−C coupling of monohydric alcohols
Catalysis Communications, 2021 Monohydric alcohols, such as methanol, ethanol, are useful chemical building blocks that can be facilely produced from various carbon resources. The direct conversion of alcohols into high-value-added chemicals, in particular diols, is attractive but ...
Limei Wang +5 more
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Au-Catalyzed Cross-Coupling of Arenes via Double C–H Activation [PDF]
Journal of the American Chemical Society, 2015 The first methodology for Au(I/III)-catalyzed oxidative cross-coupling of arenes via double C-H activation has been developed. The reaction is fully selective for the cross-coupling between electron-rich hetero-/carbocyclic arenes and electron-poor arenes bearing relatively acidic C-H bonds.
Cambeiro, XC, Ahlsten, N, Larrosa, I
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Strategies to transform remote C(sp3)-H bonds of amino acid derivatives
Tetrahedron Chem, 2022 Amino acids and peptides play an important role in nature as well as in the pharmaceutical industry. Therefore, transformation of amino acids and peptides into their unnatural derivatives via step and atom economical ways is highly demanding. Although, a
Supreeta Sen +2 more
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When transition-metal-catalyzed C–H activation meets allene chemistry
Tetrahedron Chem, 2023 Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative CCC bonds.
Shu-Meng Deng +2 more
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Functionalization of Porphyrins Using Metal-Catalyzed C–H Activation
Inorganics, 2022 The review is devoted to the C–H functionalization of porphyrins. Porphyrins exhibit the properties of organic semiconductors, light energy converters, chemical and electrochemical catalysts, and photocatalysts.
Aleksey N. Kiselev +3 more
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Molecules, 2021 Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
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A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle [PDF]
Royal Society Open Science, 2016 The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine.
Gavin W. Roffe +10 more
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