Results 111 to 120 of about 28,217,704 (208)

Palladium-catalyzed picolinamide-directed iodination of remote ortho-C−H bonds of arenes: Synthesis of tetrahydroquinolines

open access: yesBeilstein Journal of Organic Chemistry, 2016
A new palladium-catalyzed picolinamide (PA)-directed ortho-iodination reaction of ε-C(sp2)−H bonds of γ-arylpropylamine substrates is reported. This reaction proceeds selectively with a variety of γ-arylpropylamines bearing strongly electron-donating or ...
William A. Nack   +4 more
doaj   +1 more source

C−H Arylation and Methylation of Pivalophenone N−H Imines

open access: yes, 2019
Iron‐catalyzed ortho C−H arylation and methylation reactions of pivalophenone N−H imines are reported. The pivaloyl N−H imine proved an excellent directing group for the arylation with diarylzinc reagents in the presence of an iron‐diphosphine catalyst ...
Wengang Xu   +3 more
core   +1 more source

Well‐Defined Nickel Precatalysts: Form, Function, and Application

open access: yesChemistry – A European Journal, Volume 32, Issue 41, 3 November 2026.
This review provides guidance on which nickel precatalysts to choose for a given application or which properties to prioritize in reaction development. A summary of the ease of synthesis, stability, diversity, accessibility, modularity, and general applicability is provided along with a related infographic.
Morgan E. John   +3 more
wiley   +1 more source

Thioketone-directed rhodium(I) catalyzed enantioselective C-H bond arylation of ferrocenes

open access: yesNature Communications, 2019
The development of straightforward methods for the synthesis of planar chiral ferrocenes remains highly challenging. Here, the authors report a rhodium(I)/phosphonate-catalyzed thioketone-directed enantioselective C-H bond arylation reaction for the ...
Zhong-Jian Cai   +4 more
doaj   +1 more source

Photochemical and Thermal Activation of a Diarylbismuth Azide

open access: yesChemistry – A European Journal, Volume 32, Issue 41, 3 November 2026.
We report the synthesis and characterization of a novel diarylbismuth azide and its divergent reactivity upon thermal or photochemical activation. These findings contribute expanding the reactivity landscape of heavy pnictogen compounds and sets the basis for further investigations. ABSTRACT Azides are widely employed in synthesis as convenient nitrene
Giacomo Pugliese   +5 more
wiley   +1 more source

Regio‐ and Chemoselective Palladium‐Catalyzed Additive‐Free Direct C─H Functionalization of Heterocycles with Chloroaryl Triflates Using Pyrazole‐Alkyl Phosphine Ligands

open access: yesAdvanced Science
A series of new pyrazole‐alkyl phosphine ligands with varying cycloalkyl ring sizes that enable additive‐free regio‐ and chemoselective C─H arylation of heterocycles are reported.
Changxue Gu, Chau Ming So
doaj   +1 more source

Infrared Irradiation‐Assisted Pd‐Catalyzed C(sp3)─H Arylation and Tandem Cyclization of Ortho‐Tolualdehydes

open access: yesChemistry – A European Journal, Volume 32, Issue 41, 3 November 2026.
A rapid and efficient protocol for the synthesis of 2‐benzylbenzaldehydes and anthracenes is reported, based on the infrared (IR) irradiation‐assisted Pd‐catalyzed C(sp3)─H arylation and the tandem C(sp3)─H arylation/electrophilic aromatic cyclization of ortho‐tolualdehydes with aryl iodides via a transient directing group (TGD) strategy.
Matteo Renato Martina   +6 more
wiley   +1 more source

Direct C–H arylation: a “Greener” approach towards facile synthesis of organic semiconducting molecules and polymers

open access: yes, 2017
Direct C–H arylation enables “greener” synthesis of π-conjugated small molecules and polymers without tedious preactivation of C–H bonds.
Mingfeng Wang, Hassan Bohra
core   +1 more source

Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H Activation

open access: yes, 2016
Palladium-Catalyzed Intramolecular Direct Arylation of Benzoic Acids by Tandem Decarboxylation/C−H ...
Frank Glorius (1555042)   +2 more
core   +1 more source

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