Challenges and Perspectives for an Extended Use of the Dye‐Sensitized Solar Cells
DSSC is a photoelectrochemical technology that will support the energy transition. DSSCs initiated the building‐integrated photovoltaics sector and are now proposed in agrivoltaics, archaeophotovoltaics and as indoor solution for powering the Internet of Things. The wavelength selectivity for photoconversion renders DSSCs unique in photovoltaics ambit.
Danilo Dini +6 more
wiley +1 more source
Tris(indol‐3‐yl)methanes were synthesized from indoles, CO2, and PhMe2SiH in the presence of BPh3 in acetonitrile at 50°C. One product, tris(4‐bromo‐1‐methylindol‐3‐yl)methane, underwent a palladium‐catalyzed cascade reaction for the formation of a novel polycyclic heteroaromatic compound, where the methine C(sp3) atom originating from CO2 was ...
Sha Li +5 more
wiley +1 more source
Effect of α-Substitution on the Reactivity of C(sp3)-H Bonds in Pd0-Catalyzed C-H Arylation. [PDF]
Wheatley M +4 more
europepmc +1 more source
Synthesis, Updated Characterization, and Reactivity of Low‐Valent Titanocene Complexes
Syntheses and characterizations are provided for a series of low‐valent titanocene complexes including halotitanocene(III) dimers, [Cp2Ti(κ2‐DME)][BAr4] cations, and heterobimetallic [Cp2Ti(μ‐Cl)2AlR2]. Additionally, a monomeric titanacyclopropene complex featuring a pendent phosphine was prepared, and C─F bond activation upon reduction of [Cp{η5:κ2F2 ...
Griffin J. LaChapelle +2 more
wiley +1 more source
Author Correction: Expanding chemical space by para-C-H arylation of arenes. [PDF]
Maiti S +7 more
europepmc +1 more source
Synthetic Strategies for the Construction of Cyclobutane‐Fused Heterocycles
Cyclobutane‐fused heterocycles are important motifs commonly present in bioactive compounds, recognized for their rigid 3D structures that confer unique properties. However, synthesizing these compounds remains challenging. This review discusses current methods for their synthesis, such as photochemical, metal‐catalyzed, and Lewis acid‐mediated [2 + 2]
Michela Vargiu +2 more
wiley +1 more source
Site-Selective C-H Arylation of Diverse Arenes Ortho to Small Alkyl Groups. [PDF]
Dhankhar J +3 more
europepmc +1 more source
Selective N‐Functionalization of Pyrazoles
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek +2 more
wiley +1 more source
Formal β-C-H Arylation of Aldehydes and Ketones by Cooperative Nickel and Photoredox Catalysis. [PDF]
Liu K, Studer A.
europepmc +1 more source
Modular Synthesis of Di‐ and Triazadibenzoazulenes by a Cross‐Coupling/Cycloisomerization Strategy
Two series of regioisomeric di‐ and triazadibenzoazulenes were prepared from dihalogenated imidazo[1,2‐a]pyridines and imidazo[1,2‐a]pyrazines. Imidazo[1,2‐a]pyridines and imidazo[1,2‐a]pyrazines are important nitrogen‐containing heterocycles with applications in medicinal and materials chemistry.
Karyna Kulyk +6 more
wiley +1 more source

