Recent Applications of Propylene Carbonate as a Solvent in Sustainable Organic Synthesis
ChemSusChem, Volume 19, Issue 17, 14 September 2026.This review evaluates propylene carbonate (PC) as a non‐toxic green solvent in organic synthesis, highlighting its performance in key reactions including cross‐couplings, asymmetric hydrogenations, peptide synthesis and biocatalysis. Across these processes, PC delivers yields comparable to conventional and alternative green solvents.
Laura G. Aguilar‐Sanchez +1 more
wiley +1 more source
Rational ligand modification maximizes turnover rate in a model Pd-catalyzed C-H arylation. [PDF]
iScience, 2023 Beckers I, De Vos D.
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Infrared Irradiation‐Assisted Sonogashira Cross‐Coupling Reaction
ChemSusChem, Volume 19, Issue 17, 14 September 2026.The Pd‐catalyzed Sonogashira cross‐coupling was developed under sustainable conditions using IR irradiation in water and a recyclable Pd/C catalyst. The protocol promotes efficient C(sp2)─C(sp) bond formation under mild conditions with low Pd loading (1 mol%), providing good to excellent yields for various aryl iodides and terminal alkynes.
Ambra M. Fiore +4 more
wiley +1 more source
Supported Eosin Y as a Photocatalyst for C-H Arylation of Furan in Batch and Flow. [PDF]
Molecules, 2022 Rossi S, Herbrik F, Resta S, Puglisi A.
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Angewandte Chemie International Edition, Volume 65, Issue 37, 7 September 2026.An anomeric amide‐enabled divergent aldehyde functionalization sequence provides one‐pot access to unsymmetrical ureas, carbamates, thiocarbamates, thioesters, and amides. Key to this transformation is the formation of N‐Boc‐hydroxamate intermediates, which serve as platforms for orthogonal activation via Lossen‐type rearrangements, single‐electron ...
Jasper L. Tyler +6 more
wiley +1 more source
From Sourcing to End‐of‐Life: Sustainability Challenges and Opportunities in Organic Bioelectronics
Advanced Science, Volume 13, Issue 51, 14 September 2026.Organic bioelectronics bridges biology and electronics using organic mixed ionic/electronic conductors. This Perspective addresses sustainability across the full lifecycle of organic bioelectronic materials and devices, offering a framework to guide material sourcing, synthesis, fabrication, application, and end‐of‐life strategies toward bioelectronic ...
Gwennaël Dufil +3 more
wiley +1 more source
Advanced Energy Materials, Volume 16, Issue 34, 9 September 2026.Fluorination of polytriphenylamine lowers the HOMO energy, enabling high‐voltage operation of the PFTPA cathode. Electron‐withdrawing F substituents stabilize the nitrogen redox center and suppress polarization, leading to fast kinetics. The optimized polymer delivers ∼3.75 V vs.
Natalia Voronina +6 more
wiley +1 more source
A facile tert-butyl nitrite-assisted preparation of deamino graphitic carbon nitride (DA-gCN) as a photocatalyst for the C-H arylation of heteroarenes using anilines as radical source. [PDF]
Turk J Chem, 2023 Natarajan P, Karapinar Koç B, Metin Ö.
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Machine Learning for Synthetic Organic Chemistry: Methods, Applications, and Best Practices
Angewandte Chemie Novit, Volume 2, Issue 3, September 2026.Artificial intelligence (AI) and machine learning (ML) are increasingly reshaping experimental chemistry. This review maps the challenges of synthetic organic chemistry to modern digital tools that can help address them. While focusing on the practical application of ML tools in real‐world laboratory settings, we outline prerequisites, emerging ...
Niklas Hölter +3 more
wiley +1 more source
S,O-Ligand Promoted meta-C-H Arylation of Anisole Derivatives via Palladium/Norbornene Catalysis. [PDF]
Angew Chem Int Ed Engl, 2022 Sukowski V +3 more
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