Results 11 to 20 of about 616,215 (256)
Photocatalytic C−H activation and C−C coupling of monohydric alcohols
Monohydric alcohols, such as methanol, ethanol, are useful chemical building blocks that can be facilely produced from various carbon resources. The direct conversion of alcohols into high-value-added chemicals, in particular diols, is attractive but ...
Limei Wang +5 more
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TiO2 Nanoparticles Enabling Photocatalytic Desulfurization for C–C Coupling Reaction Using Visible Light [PDF]
Shea Stewart +4 more
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Control over both dispersion and the particle size distribution of supported metal particles is of paramount importance for the catalytic activity of composite materials.
Surjyakanta Rana +2 more
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Murahashi Cross‐Coupling at −78 °C: A One‐Pot Procedure for Sequential C−C/C−C, C−C/C−N, and C−C/C−S Cross‐Coupling of Bromo‐Chloro‐Arenes [PDF]
AbstractThe coupling of organolithium reagents, including strongly hindered examples, at cryogenic temperatures (as low as −78 °C) has been achieved with high‐reactivity Pd‐NHC catalysts. A temperature‐dependent chemoselectivity trigger has been developed for the selective coupling of aryl bromides in the presence of chlorides.
Narayan Sinha +3 more
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Oxidative electrochemical aryl C–C coupling of spiropyrans [PDF]
The isolation and definitive assignment of the species formed upon electrochemical oxidation of nitro-spiropyran (SP) is reported. The oxidative aryl C-C coupling at the indoline moiety of the radical cation to form covalent dimers of the ring-closed form is demonstrated. The coupling is blocked with a methyl substituent para to the indoline nitrogen.
Ivashenko, Oleksii +4 more
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A concise and efficient photocatalytic C–C coupling of 1-benzyl-3-cyano-1, 4-dihydropyridine for synthesis of 1,1′-dibenzyl-3, 3′-dicyano-1,1′,4,4′-tetrahydro-4, 4′-bipyridine is described.
Shijun Chen +5 more
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Selective C−C Coupling by Spatially Confined Dimeric Metal Centers
Summary: Direct conversion of carbon dioxide (CO2) to high-energy fuels and high-value chemicals is a fascinating sustainable strategy. For most of the current electrocatalysts for CO2 reduction, however, multi-carbon products are inhibited by large ...
Yanyan Zhao, Si Zhou, Jijun Zhao
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Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling
It is of high interest to convert CO2 into valuable ethanol product. Here the authors demonstrate the asymmetric C-C coupling triggered on Ag-modified oxide-derived Cu sites can accelerate and steer the reaction pathway for ethanol production with high ...
Pengtang Wang +8 more
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Porous fixed-bed photoreactor for boosting C–C coupling in photocatalytic CO2 reduction
Solar-driven CO2 conversion to chemical fuels in an aqueous solution is restricted not only by photocatalysts but also by mass transfer. Here, a regulatable three-phase interface on a porous fixed-bed is constructed for efficient C–C coupling in ...
Shengjie Bai +6 more
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Electrocatalytic Reduction of CO2 to Value‐Added Chemicals via C–C/N Coupling
The efficient conversion and utilization of CO2 is imminent due to the increase of global CO2 emissions year by year, so the strategy of electrocatalytic CO2 reduction to high value‐added chemicals comes into being. The CO2 reduction reaction (CO2RR) can
Junling Liu +4 more
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