Undirected C-H Bond Activation in Aluminium Hydrido Enaminonates [PDF]
Molecules, 2023 Two new aluminium hydrido complexes were synthesized by reacting AlH3 with the enaminone ligand N-(4,4,4-trifluorobut-1-en-3-on)-6,6,6-trifluoroethylamine (HTFB-TFEA) in different molar ratios to obtain mono- and di-hydrido-aluminium enaminonates.
Chijioke Kingsley Amadi +4 more
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Systematic Assessment of the Catalytic Reactivity of Frustrated Lewis Pairs in C-H Bond Activation [PDF]
Molecules, 2023 Unreactive C-H bond activation is a new horizon for frustrated Lewis pair (FLP) chemistry. This study provides a systematic assessment of the catalytic reactivity of recently reported intra-molecular FLPs on the activation of typical inert C-H bonds ...
Yongjie Guo +7 more
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Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization [PDF]
Molecules, 2021 Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
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Recent Advances in the Synthesis of Cyclic Sulfoximines via C–H Bond Activation [PDF]
Molecules, 2023 Sulfoximines, a ubiquitous class of structural motifs, are widely present in bioactive molecules and functional materials that have received considerable attention from modern organic chemistry, pharmaceutical industries, and materials science ...
Bingren Wang, Xiayu Liang, Qingle Zeng
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Dehydrogenative Double C-H Bond Activation in a Germylene-Rhodium Complex*. [PDF]
Chemistry, 2021 Abstract Transition metal tetrylene complexes offer great opportunities for molecular cooperation due to the ambiphilic character of the group 14 element. Here we focus on the coordination of germylene [(Ar Mes2 ) 2 Ge :] (Ar
Bajo S +3 more
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Zinc-indium-sulfide favors efficient C − H bond activation by concerted proton-coupled electron transfer [PDF]
Nature CommunicationsC − H bond activation is a ubiquitous reaction that remains a major challenge in chemistry. Although semiconductor-based photocatalysis is promising, the C − H bond activation mechanism remains elusive.
Xuejiao Wu +7 more
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Coumarins Synthesis and Transformation via C–H Bond Activation—A Review
Inorganics, 2022 For several decades, coumarins have attracted considerable attention due to the fact of their application in diverse fields such as medical science and biomedical research as well as several industrial branches.
Katarzyna Szwaczko
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Strategies to transform remote C(sp3)-H bonds of amino acid derivatives
Tetrahedron Chem, 2022 Amino acids and peptides play an important role in nature as well as in the pharmaceutical industry. Therefore, transformation of amino acids and peptides into their unnatural derivatives via step and atom economical ways is highly demanding. Although, a
Supreeta Sen +2 more
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Divergent isoindolinone synthesis through palladium-catalyzed isocyanide bridging C–H activation
Cell Reports Physical Science, 2022 Summary: The formation of thermodynamically accessible metallacycle is crucial to achieve site-selective C–H bond activation. Here, we report an isocyanide-bridging C–H activation through the formation of a five-membered palladacycle. As such, a proximal
Fulin Zhang +6 more
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Intermolecular Radical C–H Bond Activation: A Powerful Tool for Late Stage Functionalization
CHIMIA, 2020 The synthesis of complex molecules via radical reactions involving carbon–carbon and carbon–heteroatom bonds has become a very successful approach. Radical chemistry has long been dominated by the use of tin-based reagents.
Fabrice Dénès
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