Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O2 and NOx
The oxidation of polyethylene in the presence of a mixture of O2 and NOx and with Cu2+/V5+ as catalyst yields ∼51 mol% diacids, while retaining ∼80 mol% of the carbon in the oil fraction. The developed method is robust and tolerates several polymer types as well as impurities.
Tom J. Smak +3 more
wiley +1 more source
Crystal structure and Hirshfeld surface analysis of 1-(di-methyl-amino-meth-yl)-2-(pyrrolidin-1-ylmeth-yl)ferrocene complexes with zinc(II) bromide and cadmium(II) bromide. [PDF]
Moritz B, Mairath T, Strohmann C.
europepmc +1 more source
Ein luftstabiler, einfach herzustellender bifunktioneller Cu(II)/Imidazolium‐Komplex ermöglicht hoch enantioselektive α‐Alkylierungen von 1,3‐Dicarbonylverbindungen mit herausragender Produktivität (TON bis zu 1740). Zu den hervorzuhebenden Merkmalen zählen ein breites Elektrophilspektrum, das sowohl π‐aktivierte als auch nicht aktivierte Reagenzien ...
Johanna Haußmann +8 more
wiley +1 more source
Bruceine D attenuates prostate cancer growth and motility by suppressing PI3K/AKT signaling and downregulating CXCL16: implications for skeletal metastasis in orthopedic oncology. [PDF]
Chen Z +11 more
europepmc +1 more source
Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone +8 more
wiley +1 more source
USP13 promotes enzalutamide resistance by catalyzing depolyubiquitination of PCMT1 in prostate cancer. [PDF]
Wang Z +11 more
europepmc +1 more source
Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin +3 more
wiley +1 more source
Synthesis and crystal structure of di-μ-chlorido-bis-[bis(2,6-di-methyl-pyrazine)-copper(I)] and di-μ-bromido-bis[bis(2,6-di-methyl-pyrazine)copper(I)]. [PDF]
Näther C.
europepmc +1 more source

