Results 301 to 310 of about 1,190,759 (343)
Wir stellen eine kobaltkatalysierte Radikalkaskade vor, die zwei Alken Ausgangsstoffe effizient miteinander verbindet und so in einem einzigen Schritt mehrere Bindungen aufbaut. Der Prozess beginnt mit einem kobaltkatalysierten Wasserstoffatomtransfer an eine Styrol‐Doppelbindung, gefolgt von einer Giese‐Addition.
Jingyang Qin +3 more
wiley +1 more source
Syntheses and structures of bis(2-amino-py-rimi-dine-κ<i>N</i> <sup>1</sup>)di-chlorido-zinc(II) (ortho-rhom-bic polymorph) and bis(2-am-ino-py-rimi-dine-κ<i>N</i> <sup>1</sup>)di-iodido-zinc(II). [PDF]
Näther C, Bhosekar G.
europepmc +1 more source
Consequences of Medium‐Pore Zeolite Constraints for Alkene Cracking—The Case of n‐Pentene
Alkene cracking in medium‐pore zeolites is governed by a balance of enthalpic and entropic effects. Intrinsic barriers are quantified and shown to be lower than for alkanes due to stabilization of carbenium‐ion‐like transition states. Confinement and extra‐framework aluminum modulate reactivity by tuning transition‐state energetics, providing a ...
Ruixue Zhao +4 more
wiley +1 more source
Synthesis and structure of a 1:1 1-phenyl-semicarbazide-1-phenyl-pyrazolidin-3-one cocrystal. [PDF]
Muthu S +3 more
europepmc +1 more source
From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk +4 more
wiley +1 more source
Bis{μ-1,3-bis-[dimeth-yl(pyridin-3-yl)sil-yl]propane-κ<sup>2</sup> <i>N</i>:<i>N</i>'}bis-[di-iodido-zinc(II)] from synchrotron data. [PDF]
Song J, Kim D, Lee YA.
europepmc +1 more source

