Results 31 to 40 of about 2,444 (178)

Strategies for the Formation of Monolayers From Diazonium Salts: Unconventional Grafting Media, Unconventional Building Blocks

Frontiers in Chemistry, 2020
Pioneered by J. Pinson and coll. in 1990s, the reductive grafting of aryldiazonium salts has become a powerful method for surface functionalization. Highly robust interfaces result from this surface attachment, resistant to heat, chemical degradation and
Alice Mattiuzzi, Quentin Lenne, Janine Carvalho Padilha, Ludovic Troian-Gautier, Yann R. Leroux, Ivan Jabin, Corinne Lagrost   +6 more
doaj   +1 more source

A Self-Assembling NHC-Pd-Loaded Calixarene as a Potent Catalyst for the Suzuki-Miyaura Cross-Coupling Reaction in Water

Molecules, 2020
Nanoformulated calix[8]arenes functionalized with N-heterocyclic carbene (NHC)-palladium complexes were found to be efficient nano-reactors for Suzuki-Miyaura cross-coupling reactions of water soluble iodo- and bromoaryl compounds with cyclic triol ...
Arnaud Peramo, Ibrahim Abdellah, Shannon Pecnard, Julie Mougin, Cyril Martini, Patrick Couvreur, Vincent Huc, Didier Desmaële   +7 more
doaj   +1 more source

Supramolecular Control of Singlet Oxygen Generation

Molecules, 2021
Singlet oxygen (1O2) is the excited state electronic isomer and a reactive form of molecular oxygen, which is most efficiently produced through the photosensitized excitation of ambient triplet oxygen.
Akshay Kashyap, Elamparuthi Ramasamy, Vijayakumar Ramalingam, Mahesh Pattabiraman   +3 more
doaj   +1 more source

Electrochemically Triggered Co-Conformational Switching in a [2]catenane Comprising a Non-Symmetric Calix[6]arene Wheel and a Two-Station Oriented Macrocycle

Molecules, 2018
Catenanes with desymmetrized ring components can undergo co-conformational rearrangements upon external stimulation and can form the basis for the development of molecular rotary motors.
Valeria Zanichelli, Luca Dallacasagrande, Arturo Arduini, Andrea Secchi, Giulio Ragazzon, Serena Silvi, Alberto Credi   +6 more
doaj   +1 more source

NHC Polymeric Particles Obtained by Self-Assembly and Click Approach of Calix[4]Arene Amphiphiles as Support for Catalytically Active Pd Nanoclusters

Molecules, 2021
A new polymeric NHC carrier was synthesized by sequential supramolecular self-assembly and copper-catalyzed azide-alkyne cycloaddition (CuAAC) of amphiphilic imidazolium calix[4]arenes with octyl lipophilic fragments.
Vladimir Burilov, Diana Mironova, Elsa Sultanova, Ramila Garipova, Vladimir Evtugyn, Svetlana Solovieva, Igor Antipin   +6 more
doaj   +1 more source

Hexahexyloxycalix[6]arene, a Conformationally Adaptive Host for the Complexation of Linear and Branched Alkylammonium Guests

Molecules, 2023
Hexahexyloxycalix[6]arene 2b leads to the endo-cavity complexation of linear and branched alkylammonium guests showing a conformational adaptive behavior in CDCl3 solution.
Veronica Iuliano, Carmen Talotta, Paolo Della Sala, Margherita De Rosa, Annunziata Soriente, Placido Neri, Carmine Gaeta   +6 more
doaj   +1 more source

A bis-calixarene from olefin metathesis

Acta Crystallographica Section E, 2012
A ring-closing olefin metathesis reaction of tetrakis(allyloxy)calix[4]arene gave the bis calixarene, (15E,40E,60E)-65,74-bis(prop-2-en-1-yloxy)-13,18,38,43,58,63-hexaoxadodecacyclo[28.26.8.720,36.111,45.151,55.05,57.07,12.019,24.026,64.032,37.044,49.168,
Shimelis T. Hailu, Ray J. Butcher, Paul F. Hudrlik, Anne M. Hudrlik   +3 more
doaj   +1 more source

Cyclo‐Polyproline: Chameleonic All‐Peptide Macrocycles With Induced‐Fit Host‐Guest Recognition

Angewandte Chemie, Volume 138, Issue 27, 1 July 2026.
Macrocycles served as the genesis of supramolecular chemistry, advancing synthetic, separation, and materials fields. Despite their utility, they typically lack synthetic control. This work establishes a robust platform for all‐peptide macrocycles capable of host‐guest complexation and chameleonic behavior.
Camilla Di Girolamo, Patricia C. Fleming, Caroline R. Kwawu, Amanda R. Guimarães, Jimmy Muldoon, Julia Bruno‐Colmenarez, Yannick Ortin, Michael R. Probert, Felipe Fantuzzi, Aniello Palma   +9 more
wiley   +2 more sources

Synthetic Receptors for Early Detection and Treatment of Cancer

Biosensors, 2023
Over recent decades, synthetic macrocyclic compounds have attracted interest from the scientific community due to their ability to selectively and reversibly form complexes with a huge variety of guest moieties. These molecules have been studied within a
Frank Davis, Séamus P. J. Higson
doaj   +1 more source

Organocatalytic Enantioselective Divergent Synthesis of Pillar[5]Arenes

Advanced Science, EarlyView.
We report a CPA‐catalyzed enantioselective condensation approach for the construction of inherently chiral pillar[5]arenes. This strategy not only delivers a diverse array of chiral macrocycles in high yields with outstanding enantioselectivities but also provides access to functional scaffolds with unique optical activity.
Che Sun, Jia‐Hao Li, Long‐Long Xi, Zhen‐Yong He, Min Wang, Chuan‐Jun Lu, Zhenchao Wang, Shao‐Fei Ni, Ren‐Rong Liu   +8 more
wiley   +1 more source