Results 81 to 90 of about 10,543 (208)
Cation Complexation by Calixarenes
The present survey summarizes some of the most relevant properties of calixarenes as cation ligands that strongly contributed to the success of this class of synthetic receptors in supramolecular chemistry.
SANSONE, Francesco +5 more
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Synthesis of N-phtaloyl amino acid p-tert-butylcalix[4]arene esters
1-3-Diesters of p-tert-butylcalix[4]arene were obtained upon reaction with N-phtaloyl amino acid chlorides. Reactions with chiral amino acids were accompanied by complete or partial racemization in the reaction media (Et3N/CH2Cl2).
Lazzarotto Márcio +2 more
doaj
Conjugates of calixarenes emerging as molecular entities of nanoscience
Calixarenes, along with cyclodextrins (viz. β-CD) and crown ethers, are the most commonly studied macrocyclic compounds. These bucket shaped molecules have gained tremendous importance for having both hydrophilic and hydrophobic compartments together in ...
Rao, Chebrolu Pulla +2 more
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Efficient Synthesis of Water-Soluble Calixarenes Using Click Chemistry
Several water-soluble calix[4]arenes were synthesized via Huisgen 1,3-dipolar cycloaddition between azides and alkynes. Cationic, anionic, and nonionic calixarenes were prepared from a common azidocalixarene intermediate.
Eui-Hyun Ryu (2464642), Yan Zhao (58882)
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Bimetallic lanthanide supramolecular edifices with calixarenes
LCS
Ihringer, Frederic +2 more
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Naphthalene-Based Calixarenes: Unusual Regiochemistry of a Friedel−Crafts Alkylation
In the pursuit of naphthalene-based calixarenes, a Friedel−Crafts alkylation with unusual regiochemistry was observed. Treatment of carbinol 14 with catalytic triflic acid was expected to produce calixarenes of the class represented by 16.
Timothy E. Glass (536972) +1 more
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Adamantylated Calix[4]arenes Bearing CuAAC-Ready 2-Azidoethyl or Propargyl Functionalities
1,3-Alternate calix[4]arenes were prepared, having bulky adamantyl groups in the p-positions of all four aromatic units of the macrocycles and pairs of propargyl or 2-azidoethyl groups alternating with n-propyl groups at the phenol oxygen atoms. The step-
Alexander Gorbunov +5 more
doaj +1 more source
Supramolecular Catalysis by Calixarenes
Calixarenes, oligomeric cyclophanes derived from the condensation of phenols with formaldehyde,1,2 have been playing a prominent role in supramolecular catalysis.
L Mandolini +5 more
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The purpose of this study was to synthesize and structurally characterize ketocalixarenes (i.e., calixarenes where the bridging methylene bridges are replaced by carbonyl groups) derived from the largest “major” calixarene, namely p-tert-butylcalix[8 ...
Katerina Kogan +3 more
doaj +1 more source
Supramolecular architecture-controlled self-assemblies of calixarenes [PDF]
The controlled self-assembly of macrocyclic molecules based on calixarenes in functional supramolecular entities is an interesting topic of research in the area of supramolecular chemistry and nanotechnology.
Yushkova E. +3 more
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