Results 101 to 110 of about 810 (205)

Gibbs energy minimization thermodynamics for CO2 capture by aqueous amines: Conservation laws, concentration variables, and parameter consistency

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
We clarify how Gibbs‐energy‐minimization models for aqueous‐amine CO2 capture fail when conservation constraints and concentration conventions are inconsistent. Exact standard‐state conversions and Reaktoro case studies show that P(CO2)‐loading fits can mask non‐unique parameters and wrong speciation, motivating complete water‐inclusive formulations ...
William R. Smith   +2 more
wiley   +1 more source

Mechanistic insights across curing regimes for enzymatic and biopolymer‐optimized reinforcement in rock masses

open access: yesDeep Underground Science and Engineering, EarlyView.
This study examines the effects of curing temperature on the mechanical behavior of underground rock masses treated with enzyme‐induced calcite precipitation (EICP) and an innovative biopolymer‐modified EICP (BP‐EICP). Abstract Biocementation is an innovative and sustainable technique for reinforcing weak and weathered rock masses in natural and ...
Mary C. Ngoma, Oladoyin Kolawole
wiley   +1 more source

Molecular Modification Strategies for CO2 Electroreduction to C2+ Products: Classifications, Mechanisms, Advances, and Perspectives

open access: yesEcoEnergy, EarlyView.
This review comprehensively outlines molecular modification strategies for steering CO2 electroreduction toward C2+ products, including the classification of diverse molecular structures, elucidation of their roles in microenvironment regulation, dissection of C–C coupling pathway engineering, and forward‐looking perspectives on machine learning and ...
Lingling Peng, Hanwen Liu, Tianyou Peng
wiley   +1 more source

Nonthermal Plasma–Enabled Cascade N2 Activation and Electroreduction

open access: yesEcoEnergy, EarlyView.
Integrating plasma‐assisted NOx synthesis with subsequent electrochemical reduction enables the sustainable synthesis of high‐value N‐containing chemicals under ambient conditions. ABSTRACT The development of sustainable nitrogen fixation technologies operating under ambient conditions is critical for reducing the energy intensity and carbon footprint ...
Shijia Li, Wei Gao, Ziyun Wang
wiley   +1 more source

Air Stability of Sulfide Solid Electrolytes: From Theoretical Insights to Practical Solutions

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This paper reviews research progress on the air stability of SSEs, covering their instability mechanisms and modification strategies, while outlining core challenges and future directions for practical applications. Sulfide solid electrolytes are pivotal for enabling high‐performance all‐solid‐state batteries due to their high ionic conductivity and ...
Hongbing Ding   +10 more
wiley   +1 more source

Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley   +1 more source

Chiral HPLC Separation of Phosphonothrixin and Phosphonate Derivatives and Electronic Circular Dichroism Characterization of the Isolated Enantiomers

open access: yesELECTROPHORESIS, EarlyView.
Natural compound phosphonothrixin's herbicidal activity resides exclusively in its (S)‐enantiomer, yet existing enantioselective syntheses are cumbersome, and direct chiral LC separation is hampered by the compound's high polarity, lack of aromatic groups, and metal chelation–induced peak tailing.
Mirna Maalouf   +8 more
wiley   +1 more source

Monitoring and Mitigation Strategies for Hazardous Compounds in Chinese Rice Wine (Huangjiu): A Comprehensive Review

open access: yesFood Safety and Health, EarlyView.
This review elucidates the formation pathways and detection technologies for ethyl carbamate, biogenic amines, and higher alcohols in Huangjiu. It concludes that integrated control frameworks are essential to decouple safety risks from the metabolic processes responsible for flavor development.
Lulu Liu   +5 more
wiley   +1 more source

Advancing Therapies for Mycobacterial Diseases: From Small Molecules to Host‐Directed Strategies

open access: yesMedicinal Research Reviews, EarlyView.
ABSTRACT The global burden of multidrug‐resistant tuberculosis (MDR‐TB) and the rising incidence of nontuberculous mycobacterial (NTM) infections highlight the urgent need for innovative therapeutic strategies. Current treatments are prolonged, toxic, and increasingly compromised by resistance and limited diagnostic capacity.
Tânia Silva   +23 more
wiley   +1 more source

Sensitivity of Irish Pyrenopeziza brassicae populations to methyl benzimidazole carbamate (MBC), quinone outside inhibitor (QoI) and succinate dehydrogenase inhibitor (SDHI) fungicides

open access: yesPest Management Science, EarlyView.
For three collections of Irish Pyrenopeziza brassicae populations fungicide sensitivity status to methyl benzimidazole carbamate (MBC), quinone outside inhibitor (QoI) and succinate dehydrogenase inhibitor (SDHI) fungicides was determined using sensitivity screening in vitro. Molecular mechanisms of insensitivity have been identified for MBC and QoI in
Diana E Bucur   +3 more
wiley   +1 more source

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