Results 61 to 70 of about 6,501 (234)

Hydration‐Gated Photoinduced Electron Transfer in BODIPY Dyes

open access: yesAngewandte Chemie, EarlyView.
Hydration switches photoinduced electron transfer (PET) ON in alkoxy‐coordinated BODIPY dyes via specific hydrogen bonding. This gating yields a fluorescence lifetime span of ∼6 ns, enabling fluorescence lifetime imaging microscopy (FLIM) contrast in live cells and organoids. ABSTRACT Fluorescent probes based on photoinduced electron transfer (PET) are
Venkata N. K. Mamillapalli   +9 more
wiley   +2 more sources

Improved Hole Transport Layer Surface by Carbazole Ammonium Treatment for 988 nm Near‐Infrared Tin‐Lead Perovskite LEDs

open access: yesAdvanced Electronic Materials, EarlyView.
Carbazole ammonium molecule treatment on PEDOT:PSS hole transport layer endows improved tin‐lead perovskite crystallization and interface transport for near‐infrared LED devices. ABSTRACT Incorporating tin (Sn) and lead (Pb) into metal halide perovskites is an effective strategy for reducing bandgap energy, enabling applications in the near‐infrared ...
Jiale Chen   +9 more
wiley   +1 more source

Axially Chiral Nonalternant Polycyclic Aromatic Hydrocarbon With Consecutive Pentagons Exhibiting Large Spin‐Polarized Current

open access: yesAngewandte Chemie, EarlyView.
Here we report two nonalternant polycyclic aromatic hydrocarbons (PAH) (1 and 2), which contain two and four consecutive pentagons, respectively. Under acidic conditions, 1 and 2 dimerize to afford the axially chiral dimers AC1 and AC2. The central azulene moiety in both 2 and AC2 shows an unusually short transannular bond of 1.366 Å.
Chang Wang   +3 more
wiley   +2 more sources

Pairing Non‐Fullerene Acceptors With the Right Polymer: Impact of Phase Morphology and Short‐Range Transport on Charge Generation

open access: yesAdvanced Electronic Materials, EarlyView.
This study investigates polymer requirements for pairing with high‐efficiency non‐fullerene acceptors (NFA) in organic photovoltaics by comparing three polymer blends across varied phase morphologies. The generation of free charges is driven by fast transport‐assisted charge separation combined with slow intrinsic recombination.
Yufei Zhong   +9 more
wiley   +1 more source

Molecular Engineering of a Mixed‐Spacer System Toward High‐Performance Polycarbazole Anion‐Exchange Membranes

open access: yesAngewandte Chemie, EarlyView.
Mixed‐spacer polycarbazole membranes balance conductivity, swelling, and stability by tuning hydration and ionic connectivity. The optimized membrane reaches 184 mS cm−1 hydroxide conductivity and 2.51 W cm−2 peak power density, offering a promising strategy for high‐performance ether‐free AEMs.
Hao Liu   +12 more
wiley   +2 more sources

Rational Backbone Planarization for Doping‐Resilient Polymeric Hole Transport Materials Toward Stable and Scalable Perovskite Solar Cells

open access: yesAdvanced Energy Materials, EarlyView.
Incorporating divinylbenzene into PTAA‐based copolymers induces backbone planarization and promotes polaron delocalization, leading to enhanced doping resilience and stabilized electronic structure. The resulting hole‐transport material, PDVB14, maintains robust performance under high dopant concentrations and prolonged device operation, offering a ...
Chanhyeok Kim   +10 more
wiley   +1 more source

Luminescence Vapochromism of a Cu(I)/Na Phosphane Iodide Assembly Based on a Secondary‐Sphere Sodium Response

open access: yesAngewandte Chemie, EarlyView.
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen   +10 more
wiley   +2 more sources

N-thioalkylcarbazoles derivatives as new anti-proliferative agents: synthesis, characterisation and molecular mechanism evaluation

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry, 2018
Synthetic or natural carbazole derivatives constitute an interesting class of heterocycles, which showed several pharmaceutical properties and occupied a promising place as antitumour tools in preclinical studies. They target several cellular key-points,
Maria Stefania Sinicropi   +11 more
doaj   +1 more source

Investigation of Polycarbazoles Thin Films Prepared by Electrochemical Oxidation of Synthesized Carbazole Derivatives

open access: yesFrontiers in Materials, 2019
Polycarbazole and its derivatives have advantages of good environmental stability, electrochromic properties and photoconductivity which have attracted considerable attention because of their potential industrial applications in electroluminescent ...
Emmanuel Contal   +5 more
doaj   +1 more source

Amorphous π‐Conjugated Passivator Facilitates Widening Process Window for Reliable Perovskite Solar Modules

open access: yesAdvanced Energy Materials, EarlyView.
A wide process window is essential for the commercialization of perovskite photovoltaics. Here, we demonstrate an amorphous π‐conjugated passivator having an asymmetric mono‐iodine substituent on a carbazole moiety imparts a high dipole moment, desirable molecular energy levels, and high thickness tolerance, thereby enabling a wide process window in ...
Hyun Seo Kim   +17 more
wiley   +1 more source

Home - About - Disclaimer - Privacy