Results 81 to 90 of about 2,756 (235)

Architecting Anisotropic Force‐Responsive Bidirectional High‐Contrast Three‐Color Fluorescence Switches via Effective Molecular Modulation for High‐Security Information Storage

open access: yesAdvanced Science, EarlyView.
Synergistically integrating substituent variation and positional isomerism in molecular engineering affords 13 rare tricolored mechanofluorochromic luminogens, and 3 exceedingly scarce force‐triggered bidirectional high‐contrast three‐color fluorescence switches are screened out via a three‐step protocol.
Yijie Zou   +7 more
wiley   +1 more source

Synthesis of 2‑Formyl Carbazoles via Tandem Reaction of Indolyl Nitrones with 2‑Methylidene Cyclic Carbonate

open access: yes
The synthesis of functionalized carbazoles as privileged nitrogen heterocycles has emerged as a central topic in drug discovery and material science. We herein disclose the rhodium­(III)-catalyzed cross-coupling reaction between indolyl nitrones and 2 ...
Amitava Rakshit (4046665)   +7 more
core   +2 more sources

Diastereoselective Rearomative Etherifications and Aminations of 2,3,9,9a-Tetrahydro-1H-carbazoles [PDF]

open access: yes
Herein we present a rearomative diastereoselective etherification/amination reaction of 2,3,9,9a-tetrahydro-1H-carbazoles, themselves accessible via the Diels-Alder reaction of N-protected 3-vinyl-1H-indoles.
Abualnaja M   +6 more
core   +4 more sources

Cobalt‐Catalyzed C─N Bond Formation via Metal‐Hydride Hydrogen Atom Transfer (MHAT)

open access: yesAngewandte Chemie, EarlyView.
Cobalt‐catalyzed metal‐hydride hydrogen atom transfer (Co‐MHAT) converts simple alkenes into C─N bonds under mild, near‐neutral conditions. A shared Co─H‐initiated radical/organocobalt intermediate is channeled into radical trapping, radical‐polar crossover, or radical ligand transfer, unifying hydroamination, hydroazidation, hydroamidation, and remote
Arman Khosravi, Ming‐Yu Ngai
wiley   +2 more sources

Catalytic condensation for the formation of polycyclic heteroaromatic compounds

open access: yesNature Communications, 2018
The development of novel chemical reactions converting biomass-derived alcohols into important classes of compounds is a particularly attractive strategy.
Daniel Forberg   +2 more
doaj   +1 more source

Theoretical investigation on hole-transporting properties of multitriphenylamine-substituted carbazoles,dibenzofurans, and dibenzothiophens

open access: yes上海师范大学学报. 自然科学版, 2017
Structural and optoelectronic properties of the multi-triphenylamine-substituted carbazoles,dibenzofurans,and dibenzothiophens,namely TnC、TnDF、TnDT (n=1~4),were investigated by the density functional theory (DFT) calculations.The results show that these ...
Han Lizhi   +4 more
doaj   +1 more source

The vilsmeier reaction of carbazoles using microwaves [PDF]

open access: yes, 2015
application/pdf9-Formylcarbazole was obtained by the reaction of carbazole with N,N-dimethylformamide and phosphorus oxychloride in good yields under microwave irradiation.
245   +7 more
core   +1 more source

Improved Hole Transport Layer Surface by Carbazole Ammonium Treatment for 988 nm Near‐Infrared Tin‐Lead Perovskite LEDs

open access: yesAdvanced Electronic Materials, EarlyView.
Carbazole ammonium molecule treatment on PEDOT:PSS hole transport layer endows improved tin‐lead perovskite crystallization and interface transport for near‐infrared LED devices. ABSTRACT Incorporating tin (Sn) and lead (Pb) into metal halide perovskites is an effective strategy for reducing bandgap energy, enabling applications in the near‐infrared ...
Jiale Chen   +9 more
wiley   +1 more source

Hydration‐Gated Photoinduced Electron Transfer in BODIPY Dyes

open access: yesAngewandte Chemie, EarlyView.
Hydration switches photoinduced electron transfer (PET) ON in alkoxy‐coordinated BODIPY dyes via specific hydrogen bonding. This gating yields a fluorescence lifetime span of ∼6 ns, enabling fluorescence lifetime imaging microscopy (FLIM) contrast in live cells and organoids. ABSTRACT Fluorescent probes based on photoinduced electron transfer (PET) are
Venkata N. K. Mamillapalli   +9 more
wiley   +2 more sources

Pairing Non‐Fullerene Acceptors With the Right Polymer: Impact of Phase Morphology and Short‐Range Transport on Charge Generation

open access: yesAdvanced Electronic Materials, EarlyView.
This study investigates polymer requirements for pairing with high‐efficiency non‐fullerene acceptors (NFA) in organic photovoltaics by comparing three polymer blends across varied phase morphologies. The generation of free charges is driven by fast transport‐assisted charge separation combined with slow intrinsic recombination.
Yufei Zhong   +9 more
wiley   +1 more source

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