Results 191 to 200 of about 27,691 (270)
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Feeding Carbonylation with CO2 via the Synergy of Single-Site/Nanocluster Catalysts in a Photosensitizing MOF.

Journal of the American Chemical Society, 2021
Solar-driven carbonylation with CO2 replacing toxic CO as a C1 source is of considerable interest; however it remains a great challenge due to the inert CO2 molecule. Herein, we integrate cobalt single-site and ultrafine CuPd nanocluster catalysts into a
Shanshan Fu   +6 more
semanticscholar   +1 more source

Palladium-Catalyzed Asymmetric Dearomative Carbonylation of Indoles.

Organic Letters, 2022
Herein, we disclose a strategy for the asymmetric dearomatization of N-arylacyl indoles via a palladium-catalyzed tandem Heck/carbonylation, leading to an array of indoline-3-carboxylates bearing vicinal C2-aza-quaternary and C3 tertiary stereocenters in
Qiu-Xiao Li   +5 more
semanticscholar   +1 more source

Electrochemical Palladium-Catalyzed Oxidative Sonogashira Carbonylation of Arylhydrazines and Alkynes to Ynones.

Journal of the American Chemical Society, 2021
Oxidative carbonylation using carbon monoxide has evolved as an attractive tool to valuable carbonyl-containing compounds, while mixing CO with a stoichiometric amount of a chemical oxidant especially oxygen is hazardous and limits its application in ...
Yong Wu   +8 more
semanticscholar   +1 more source

Palladium-Catalyzed Perfluoroalkylative Carbonylation of Unactivated Alkenes: Access to β-Perfluoroalkyl Esters.

Angewandte Chemie, 2021
Transition-metal-catalyzed multi-component carbonylation represents an efficient strategy for the preparation of various functionalized carbonyl-containing compounds.
Youcan Zhang, H. Geng, Xiao‐Feng Wu
semanticscholar   +1 more source

Carbonyl reductase

Chemico-Biological Interactions, 2000
Carbonyl reductase (secondary-alcohol:NADP(+) oxidoreductase, EC 1.1. 1.184) belongs to the family of short chain dehydrogenases/reductases (SDR). Carbonyl reductases (CBRs) are NADPH-dependent, mostly monomeric, cytosolic enzymes with broad substrate specificity for many endogenous and xenobiotic carbonyl compounds.
G L, Forrest, B, Gonzalez
openaire   +2 more sources

Role of Brønsted Acid Sites within 8-MR of Mordenite in the Deactivation Roadmap for Dimethyl Ether Carbonylation

, 2021
Mordenite zeolite is now the most promising catalyst for the carbonylation of dimethyl ether (DME) to methyl acetate because of the excellent initial activity and selectivity, but it suffers from r...
Zaizhe Cheng   +7 more
semanticscholar   +1 more source

Oxidative Carbonylations

ChemInform, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
GABRIELE, Bartolo, SALERNO G, COSTA
openaire   +2 more sources

1,4-Carbonyl-carbonyl interactions

Experientia, 1960
Es wird gezeigt, dass die IR-Spektren gewisser 1,4-Diketone und 1,4-Ketoester abnorm hohe Carbonylfrequenzen aufweisen, was auf das Vorhandensein eines intramolekularen Feldeffekts zwischen den beiden Carbonylgruppen in diesen Verbindungen hindeutet. Die ungewohnlichen Stabilitatsverhaltnisse an C-20 der 16,22-Dicarbonyl-Steroide sind vermutlich auf ...
Y. Mazur, F. Sondheimer
openaire   +1 more source

Integrating S-scheme photocatalysis with tandem carbonylation: A green and scalable strategy for CO2 valorization

Nature Communications
The rapid increase in atmospheric CO2 levels due to industrialization underscores the urgent need for innovative carbon valorization strategies. Photocatalytic CO2 reduction presents a sustainable solution; however, conventional systems suffer from ...
Feiyan Xu   +7 more
semanticscholar   +1 more source

Synthesis of α,β-unsaturated carbonyl compounds by carbonylation reactions.

Chemical Society Reviews, 2020
α,β-Unsaturated carbonyl compounds are key building blocks in organic chemistry. Their catalytic synthesis has received significant attention during the past decades. Among the known methodologies, carbonylation reactions represent an atom-efficient tool
Shaoke Zhang, H. Neumann, M. Beller
semanticscholar   +1 more source

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