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Supraicosahedral (Metalla) Carboranes

ChemInform, 2004
AbstractFor Abstract see ChemInform Abstract in Full Text.
Alan S. F. Boyd   +10 more
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Development of carborane synthons: synthesis and chemistry of (aminoalkyl)carboranes

Inorganic Chemistry, 1992
A number of (aminoalkyl)-1,2-closo-dodecaboranes have been synthesized to provide carboranes with a functional group for covalent incorporation into structures of potential use in the treatment of cancer by boron neutron capture therapy (BNCT). (Phthalimidoalkyl)acetylenes reacted with decaborane to give the corresponding carboranes; removal of the ...
J. Gerald Wilson   +3 more
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New carboranes and phosphaboranes

Pure and Applied Chemistry, 2003
Abstract A review is presented on the new routes to the synthesis of the monocarbaboranes [arachno-6-CB9H14]–, arachno-4-CB8H14, and nido-1-CB8H12, that now have become excellent starting materials for the preparation of a family of seven-, eight-, and nine-vertex closo-monocarbaborane anions [2-CB6H7]–, [1-CB7H8]–, and [4-CB8H9]–. These
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Carboranes in the chemist's toolbox

Dalton Transactions, 2015
A carborane-fullerene dyad for organic field-effect transistors illustrates one of the many diverse areas of technology in which the special properties of these polyhedral boron clusters are being exploited.
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Thallation of carboranes

Journal of Organometallic Chemistry, 1985
Abstract The conditions of the preparation of boron—thallated 1,2-, 1,7- and 1,12-dicarba- closo -dodecaboranes(12) (trivial names “ o -, m - and p -carboranes”) have been studied. It was shown that maximum yields of the products are attained when o - and m -carboranes are treated consecutively with equimolecular amounts of mercuric oxide and ...
V.I. Bregadze   +2 more
openaire   +1 more source

Pd-Catalysed synthesis of carborane sulfides from carborane thiols

Chemical Communications
Carboranes are an interesting class of aromatic molecules with icosahedral geometry, high stability, and unique electronic effects.
Natsuki Minematsu   +2 more
openaire   +3 more sources

Cyanoethylation of carboranes

Journal of Organometallic Chemistry, 1979
Abstract The methine group of o-carboranes react with acrylonitrile and alkali catalyst to form β-cyanoethylcarboranes.
V.N. Kalinin   +2 more
openaire   +1 more source

Icosahedral carboranes. XVII. Simplified preparation of o-carborane

Inorganic Chemistry, 1972
Abstract : A new synthesis of 1,2-dicarbaclosododecaborane is described which involves the reaction of acetylene with B10H12L2 compounds in the solid state. This simplified laboratory procedure provides pure o-carborane in one step as a sublimate from the reaction mixture. (Author)
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Carboranes. III. Reactions of the Carboranes

Inorganic Chemistry, 1963
Daniel Grafstein   +6 more
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